Iron Catalyzed B-C(sp2 )-H Alkylation of Enamides
- Bertho, Sylvain
- Maazaoui, Radhouan
- Torun, Damla
- Dondasse, Ismael
- Abderrahim, Raoudha
- Gillaizeau, Isabelle
- Nicolas, Cyril
DOIAbstract
International audienceAn attractive atom-economic way was developed for the BC(sp 2)-H (fluoro)alkylation of a range of acyclic and cyclic non-aromatic enamides using either FeCl2 as a catalyst or a stoichiometric amount of low-cost iron powder. This reaction is regioselective and exhibits broad substrate scope and good functional group tolerance
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