Use of glycerin, a biodiesel industry waste, produced by vegetable oil transesterification of triglycerides in reaction catalyzed by KOH as a source of potassium for soybean.

Submitted by Rodrigo Martins Cruz (rodrigo.cruz@ufvjm.edu.br) on 2015-02-27T13:30:37Z No. of bitstreams: 5 license_url: 52 bytes, checksum: 3d480ae6c91e310daba2020f8787d6f9 (MD5) license_text: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) license_rdf: 23898 bytes, checksum: e363e809996cf46ada20da1accfcd9c7 (MD5) license.txt: 2109 bytes, checksum: aa477231e840f304454a16eb85a9235f (MD5) 58.pdf: 746870 bytes, checksum: a321db5fb286c277e81d8737f1744991 (MD5)Approved for entry into archive by Rodrigo Martins Cruz (rodrigo.cruz@ufvjm.edu.br) on 2015-02-27T19:33:17Z (GMT) No. of bitstreams: 5 license_url: 52 bytes, checksum: 3d480ae6c91e310daba2020f8787d6f9 (MD5) license_text: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) license_rdf: 23898 bytes, checksum: e363e809996cf46ada20da1accfcd9c7 (MD5) license.txt: 2109 bytes, checksum: aa477231e840f304454a16eb85a9235f (MD5) 58.pdf: 746870 bytes, checksum: a321db5fb286c277e81d8737f1744991 (MD5)Made available in DSpace on 2015-02-27T19:33:17Z (GMT). No. of bitstreams: 5 license_url: 52 bytes, checksum: 3d480ae6c91e310daba2020f8787d6f9 (MD5) license_text: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) license_rdf: 23898 bytes, checksum: e363e809996cf46ada20da1accfcd9c7 (MD5) license.txt: 2109 bytes, checksum: aa477231e840f304454a16eb85a9235f (MD5) 58.pdf: 746870 bytes, checksum: a321db5fb286c277e81d8737f1744991 (MD5) Previous issue date: 2011Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico (CNPq)O objetivo do trabalho foi avaliar os efeitos da aplica??o de glicerina proveniente da transesterifica??o de triglicer?deos de ?leo vegetal por catalisador b?sico KOH como fonte de pot?ssio (?glicerina pot?ssica?), na produtividade e na nutri??o da soja e atributos qu?micos e microbiol?gicos do solo. Foram realizados quatro experimentos, sendo dois em condi??es de campo, em Diamantina e Curvelo no estado de Minas Gerais em dois tipos de solo: Neossolo Quartzar?nico ?rtico t?pico (NQ) e Latossolo Vermelho distr?fico (LVd), respectivamente; e os outros dois experimentos em casa de vegeta??o em Diamantina, com os mesmos dois solos. Os tratamentos foram tr?s doses de ?glicerina pot?ssica? correspondentes 50, 100 e 200 % da dose recomendada de K para a soja e 100 % da dose recomendada de K na forma de cloreto de pot?ssio (KCl) e sulfato de pot?ssio (K2SO4) e um tratamento sem aplica??o de K (Controle). Realizou-se a an?lise qu?mica do solo (pH, P, K, Ca, Mg, Al, H + Al, CO e SO4-2) na colheita da soja e microbiol?gica (respira??o microbiana basal (RB), carbono da biomassa microbiana (CBM) e quociente metab?lico (qCO2)) do solo no in?cio da emerg?ncia das sementes e colheita da soja e os teores foliares dos nutrientes no florescimento da soja nos quatro experimentos, a produtividade da soja nos experimentos de campo e a produ??o por vaso e mat?ria seca nos experimentos na casa de vegeta??o. A produtividade no experimento de campo apresentou diferen?a apenas no NQ, devido ao teor baixo de K no in?cio do per?odo experimental, diferentemente do LVd que apresentava teor m?dio, enquanto no experimento na casa de vegeta??o a ?glicerina pot?ssica? promoveu produ??o de gr?os igual ao do KCl, por?m abaixo de K2SO4 e n?o proporcionou aumento na mat?ria seca da parte a?rea da soja em compara??o ?s outras fontes inorg?nicas (KCl e K2SO4). Na parte qu?mica do solo no experimento de campo a ?glicerina pot?ssica? aumentou os teores de K em ambos os solos, por?m n?o alterando os demais atributos e o estado nutricional da soja, o ?glicerina pot?ssica? supriu parte do K quando este era limitante no solo e no experimento na casa de vegeta??o a ?glicerina pot?ssica? proporcionou aumento nos teores de K no solo e nos teores foliares de K e S na soja cultivada no NQ. O efeito sobre a microbiota do solo do experimento de campo foi vari?vel, sendo que na primeira avalia??o foi alta e na ?ltima estes valores diminu?ram, mostrando que o meio ? capaz de consumir a ?glicerina pot?ssica? e os fertilizantes minerais (KCl e K2SO4). No experimento de casa de vegeta??o, a ?glicerina pot?ssica? ao final do per?odo experimental apresentou tend?ncia de se equilibrar no solo NQ e chegando ao equil?brio no LVd na atividade microbiol?gica do solo. Por?m s?o necess?rios estudos para avaliar a utiliza??o da glicerina pot?ssica em longo prazo para entender melhor a din?mica deste no solo.Disserta??o (Mestrado) ? Programa de P?s-Gradua??o em Produ??o Vegetal, Universidade Federal dos Vales do Jequitinhonha e Mucuri, 2011.ABSTRACT Glycerin is a residue of the biodiesel industry, output from the process of vegetable oil transesterification of triglycerides in basic catalyst that will lead to economic, social and environmental impacts due to increased production of biodiesel in Brazil. The objective of this study was to evaluate the application of glycerin, a biodiesel industry waste, came from vegetable oil transesterification of triglycerides by potassium hydroxide catalyst (KOH) as a source of potassium ("K glycerin") on productivity and nutrition of soybeans and on chemical and microbiological characteristics of the soil. Two experiments were conducted under field conditions in a Oxisol (Typic) soil type, at Curvelo, Minas Gerais state, Brazil, and another in the village of Diamantina, Minas Gerais state in a sand soil type (NQ). The experimental design was randomized blocks with four replications. The treatments were three doses of "glycerin K 'corresponding to 50, 100 and 200% of recommended dose of Potassium for soybean and 100% of the dose recommended in the form of KCl and K2SO4 and a treatment without application of K. The recommended dose of K2O were 120 and 80 kg ha -1 for NQ and Oxisoil, respectively. There has been carried out chemical analysis of soil (pH, P, K, Ca, Mg, Al, Al + H, CO, SO4-2) in the soybean harvest and microbiological analysis (microbial basal respiration (BR), microbial biomass carbon (CBM) and metabolic quotient (OKQ (2)) soil at two times (early emergence and soybean harvest) and soybean yield and foliar concentrations of nutrients in the flowering of soybeans. Soybean yield increased with the application of "glycerin K" when the availability of K in the soil was limited, and although lower than the mineral sources of K, it supplied in part the soybeans need for K. The soil microbiota tended to balance at the end of the cycle of soybeans with application of "glycerin K", thus not causing adverse effects on crop and soil. The "glycerin K" does not cause environmental problems to the place where it was applied, but studies are needed to evaluate its long-term use to better understand the dynamics of soil and crop productivity