Preparation, structural characterization and catalytic properties of Co/CeO2 catalysts for the steam reforming of ethanol and hydrogen production.

Submitted by Karine Ribeiro (karinelg.ribeiro@gmail.com) on 2015-04-07T18:43:03Z No. of bitstreams: 1 ARTIGO_PreparationStructuralCharacterization.pdf: 990952 bytes, checksum: 970dcdd4589a1d8ebb90e79e50774228 (MD5)Approved for entry into archive by Oliveira Flávia (flavia@sisbin.ufop.br) on 2015-04-07T19:58:43Z (GMT) No. of bitstreams: 1 ARTIGO_PreparationStructuralCharacterization.pdf: 990952 bytes, checksum: 970dcdd4589a1d8ebb90e79e50774228 (MD5)Made available in DSpace on 2015-04-14T17:50:37Z (GMT). No. of bitstreams: 1 ARTIGO_PreparationStructuralCharacterization.pdf: 990952 bytes, checksum: 970dcdd4589a1d8ebb90e79e50774228 (MD5) Previous issue date: 2012In this paper, Co/CeO2 catalysts, with different cobalt contents were prepared by the polymeric precursor method and were evaluated for the steam reforming of ethanol. The catalysts were characterized by N2 physisorption (BET method), X-ray diffraction (XRD), UVevisible diffuse reflectance, temperature programmed reduction analysis (TPR) and field emission scanning electron microscopy (FEG-SEM). It was observed that the catalytic behavior could be influenced by the experimental conditions and the nature of the catalyst employed. Physicalechemical characterizations revealed that the cobalt content of the catalyst influences the metal-support interaction which results in distinct catalyst performances. The catalyst with the highest cobalt content showed the best performance among the catalysts tested, exhibiting complete ethanol conversion, hydrogen selectivity close to 66% and good stability at a reaction temperature of 600 _C