Add to ORKGThe polymerization of ethylene on surfaces sequentially dosed with TiCl4 and trimethylaluminum was studied by Fourier transform infrared spectroscopy. The polymer film was observed in situ as a function of time and under the influence of 254-nm cw radiation. The rate of polyethylene are strongly dependent on the order of dosing and the partial pressure of the reactants that demonstrated to occur through two seperate photochemical channels; gas-phase photolysis of the reactants and solid-phase chemical transformation of a noncatalytic thin film
Plasma-treated polymers typically show changes of surface morphology as well as modifications in the...
Commercial olefin polymerization catalysts are typically produced at a manufacturing site before tra...
This paper reports on the results of measuring the changes in the characteristics of the surface of ...
The study examines chemical and structural modifications effected in the UV ablation of polymers. Fo...
AbstractIn this communication, we report the polymerization of ethylene molecules induced by an atom...
Ethylene was polymerized in slurry phase over a TiCl4/Mg(OC2H5)2 catalyst activated by Al(C2H5)3. It...
Tetraneopentyltitanium initiates slow homopolymerizations and copolymerizations of styrene and of me...
The photopolymerization of monolayers prepared at the gas-water interface with two styrene functiona...
The photodegradation of thin films of poly (4-chlorostyrene) and poly (4-bromostyrene) with 265 nm r...
Ziegler–Natta polymerization catalysts were characterized by a complex of surface- and bulk-sensitiv...
The photopolymerization of monolayers prepared at the gas-water interface with two styrene functiona...
The free-radical polymerization of styrene initiated from a functionalized poly(ethylene terephthala...
A series of CrOx/SiO2/Si(100) model catalysts were tested for ethylene polymerization activity, vary...
A planar CrOx/SiO2/Si (100) model for the Phillips ethylene polymerization catalyst, prepared by spi...
Plasma-treated polymers typically show changes of surface morphology as well as modifications in the...
Commercial olefin polymerization catalysts are typically produced at a manufacturing site before tra...
This paper reports on the results of measuring the changes in the characteristics of the surface of ...
The study examines chemical and structural modifications effected in the UV ablation of polymers. Fo...
AbstractIn this communication, we report the polymerization of ethylene molecules induced by an atom...
Ethylene was polymerized in slurry phase over a TiCl4/Mg(OC2H5)2 catalyst activated by Al(C2H5)3. It...
Tetraneopentyltitanium initiates slow homopolymerizations and copolymerizations of styrene and of me...
The photopolymerization of monolayers prepared at the gas-water interface with two styrene functiona...
The photodegradation of thin films of poly (4-chlorostyrene) and poly (4-bromostyrene) with 265 nm r...
Ziegler–Natta polymerization catalysts were characterized by a complex of surface- and bulk-sensitiv...
The photopolymerization of monolayers prepared at the gas-water interface with two styrene functiona...
The free-radical polymerization of styrene initiated from a functionalized poly(ethylene terephthala...
A series of CrOx/SiO2/Si(100) model catalysts were tested for ethylene polymerization activity, vary...
A planar CrOx/SiO2/Si (100) model for the Phillips ethylene polymerization catalyst, prepared by spi...
Plasma-treated polymers typically show changes of surface morphology as well as modifications in the...
Commercial olefin polymerization catalysts are typically produced at a manufacturing site before tra...
This paper reports on the results of measuring the changes in the characteristics of the surface of ...