Single crystals of BaLn2Te4 (Ln = Gd-Tm, Y) form as black needles from the stoichiometric reaction BaTe + 2Ln + 3Te at 1000°C. BaSm2Te4 forms as a by-product in the reaction BaTe + Sm+Zn + Te at 850°C with the aid of a BaBr2/KBr flux. The compounds crystallize with four formula units in the space group D2h16-Pnma (No. 62) in the CaFe2O4 (calcium ferrite) structure type. Unit cell constants range from a = 13.6883(10) Å, b = 4.5148(3) Å, and c = 16.3427(12) Å in the Sm compound to a = 13.5677(10) Å, b = 4.4058(3) A, and c = 15.9989(12) Å for Tm (t= -120°C). Ln atoms are coordinated by six Te atoms in an octahedral arrangement. These octahedra share corners and edges to form a three-dimensional channel structure. Ba atoms occupy the bicapped t...
Bobev, SvilenThe relationship between crystal structures, compositions and physical properties, toge...
The structure of 14 compounds in the series Ba2LnTaO6 have been examined using synchrotron X-ray dif...
This paper reports for the first time on the new laminar quaternary orthorhombic heterometallic quat...
The series of compounds in the BaLn2O4 family (Ln = La–Lu, Y) has been synthesized for the first tim...
During our exploration of kinetically stable solid state materials, we have discovered a new binary ...
Three new isostructural quaternary tellurides, Ba2Ln1-xMn2Te5 (Ln = Pr, Gd, and Yb), have been synth...
The 12 new rare-earth tellurides Ba<sub>2</sub>MLnTe<sub>5</sub> (M = Ga and Ln = Sm, Gd, Dy, Er, Y;...
International audienceThe three new solid-state compounds BaThTe4, BaUTe4, and BaUTe6 have been synt...
A fast-growing interest in solid state telluride chemistry has taken place during the past several y...
The three new solid-state compounds BaThTe<sub>4</sub>, BaUTe<sub>4</sub>, and BaUTe<sub>6</sub> hav...
Title: Magnetic properties of R2TIn8 and related tetragonal compounds Author: Petr Čermák Department...
Complex transition metals oxyhalides containing a lone pair element, such as tellurium (IV), form an...
Two new quaternary tellurides, Cs19Ln19Mn10Te48 (Ln = Pr and Gd), were synthesized by the reactive m...
Three intermetallic series with increasing rare earth dilution are examined and their magnetic and p...
The structures of eight members of the series of double perovskites of the type Ba2LnBâ?²O6 (Ln=La3+...
Bobev, SvilenThe relationship between crystal structures, compositions and physical properties, toge...
The structure of 14 compounds in the series Ba2LnTaO6 have been examined using synchrotron X-ray dif...
This paper reports for the first time on the new laminar quaternary orthorhombic heterometallic quat...
The series of compounds in the BaLn2O4 family (Ln = La–Lu, Y) has been synthesized for the first tim...
During our exploration of kinetically stable solid state materials, we have discovered a new binary ...
Three new isostructural quaternary tellurides, Ba2Ln1-xMn2Te5 (Ln = Pr, Gd, and Yb), have been synth...
The 12 new rare-earth tellurides Ba<sub>2</sub>MLnTe<sub>5</sub> (M = Ga and Ln = Sm, Gd, Dy, Er, Y;...
International audienceThe three new solid-state compounds BaThTe4, BaUTe4, and BaUTe6 have been synt...
A fast-growing interest in solid state telluride chemistry has taken place during the past several y...
The three new solid-state compounds BaThTe<sub>4</sub>, BaUTe<sub>4</sub>, and BaUTe<sub>6</sub> hav...
Title: Magnetic properties of R2TIn8 and related tetragonal compounds Author: Petr Čermák Department...
Complex transition metals oxyhalides containing a lone pair element, such as tellurium (IV), form an...
Two new quaternary tellurides, Cs19Ln19Mn10Te48 (Ln = Pr and Gd), were synthesized by the reactive m...
Three intermetallic series with increasing rare earth dilution are examined and their magnetic and p...
The structures of eight members of the series of double perovskites of the type Ba2LnBâ?²O6 (Ln=La3+...
Bobev, SvilenThe relationship between crystal structures, compositions and physical properties, toge...
The structure of 14 compounds in the series Ba2LnTaO6 have been examined using synchrotron X-ray dif...
This paper reports for the first time on the new laminar quaternary orthorhombic heterometallic quat...