These studies describe the use of the redox-active 1,1'-diamidoferrocene ligand on uranium and group 5 metals. A novel terminal uranium-imide complex was synthesized using the bulky 2,6-dimesitylphenyl imide substituent as support. Although the uranium-imide was shown to be sterically accessible through the accommodation of another 2,6-dimesitylphenyl amide group, further reactivity was not seen, with the exception of sulfur. Electron transfer between the iron contained in the 1,1'-diamidoferrocene ligand and group 5 metals was more apparent than with uranium. A control reaction between ferrocene and niobium pentachloride suggested the formation of ferrocenium via electron transfer from iron to niobium. The use of a reduced tantalum and nio...
The complex bonding and redox properties of actinide elements are much less understood compared to c...
It is well-known that f-block elements can exhibit coordination modes which surpass those of the tra...
Organometallic transformations, such as two-electron oxidative additions and reductive eliminations,...
This work culminates a systematic study of various uranium complexes supported by ferrocene diamide ...
Known primarily for its single electron chemistry, controlling the electronics at uranium to facilit...
International audienceUranyl(VI), uranyl(V), and uranium(IV) complexes supported by ferrocene-based ...
The effects of the ligand field are generally on the same order of magnitude as spin-orbit coupling ...
The effects of the ligand field are generally on the same order of magnitude as spin-orbit coupling ...
Our group has focused on the organometallic chemistry of rare-earth metals and actinides for a decad...
The work reported herein represents various studies of group 3 metal complexes supported by ferrocen...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
While transition metal complexes are known to participate in multi-electron redox chemistry to facil...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
With the ever-diminishing reserves of fossil fuels, it is inevitable that nuclear power will represe...
The collective knowledge regarding the behavior of actinides, and in particular, uranium is still ve...
The complex bonding and redox properties of actinide elements are much less understood compared to c...
It is well-known that f-block elements can exhibit coordination modes which surpass those of the tra...
Organometallic transformations, such as two-electron oxidative additions and reductive eliminations,...
This work culminates a systematic study of various uranium complexes supported by ferrocene diamide ...
Known primarily for its single electron chemistry, controlling the electronics at uranium to facilit...
International audienceUranyl(VI), uranyl(V), and uranium(IV) complexes supported by ferrocene-based ...
The effects of the ligand field are generally on the same order of magnitude as spin-orbit coupling ...
The effects of the ligand field are generally on the same order of magnitude as spin-orbit coupling ...
Our group has focused on the organometallic chemistry of rare-earth metals and actinides for a decad...
The work reported herein represents various studies of group 3 metal complexes supported by ferrocen...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
While transition metal complexes are known to participate in multi-electron redox chemistry to facil...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
With the ever-diminishing reserves of fossil fuels, it is inevitable that nuclear power will represe...
The collective knowledge regarding the behavior of actinides, and in particular, uranium is still ve...
The complex bonding and redox properties of actinide elements are much less understood compared to c...
It is well-known that f-block elements can exhibit coordination modes which surpass those of the tra...
Organometallic transformations, such as two-electron oxidative additions and reductive eliminations,...