Selenium NMR has become a standard tool for scaling the π-accepting character of carbenes. Herein, we highlight that non-classical hydrogen bonding (NCHB), likely resulting from hyperconjugation, can play a significant role in the carbene-selenium 77 Se NMR chemical shift, thus triggering a non-linear behavior of the Se-Scale
Selenium substituents which are disposed β to an electron deficient centre, such as a carbocation p-...
Selenium substituents which are disposed β to an electron deficient centre, such as a carbocation p-...
Various inorganic selenium-based compounds were analysed by Se-77 solid-state NMR, and a distinct di...
Selenium NMR has become a standard tool for scaling the π-accepting character of carbenes. Herein, w...
A new method for the assessment of the π-acceptor strength of N-heterocyclic carbenes is presented. ...
N-heterocyclic carbenes (NHCs) are common ancillary ligands in organometallic compounds that are use...
The electronic nature of the interaction of NHCs with metal centres is of interest when exploring th...
The electronic nature of the interaction of NHCs with metal centres is of interest when exploring th...
A series of novel low-valent organoselenium compounds stabilized by Se...N intramolecular interactio...
This dissertation involves the study and manipulation of molecular orbitals on ambiphilic molecules ...
A combined experimental/computational study of cooperativity between halogen-(XB) and hydrogen bondi...
The electronic nature of the interaction of NHCs with metal centres is of interest when exploring th...
Experimental Se-77 NMR parameters for 17 selenium-containing compounds have been determined by analy...
A series of novel low-valent organoselenium compounds stabilized by Se···N intramolec...
Nonbonded interactions involving selenium have been recognized for many years and are known to invol...
Selenium substituents which are disposed β to an electron deficient centre, such as a carbocation p-...
Selenium substituents which are disposed β to an electron deficient centre, such as a carbocation p-...
Various inorganic selenium-based compounds were analysed by Se-77 solid-state NMR, and a distinct di...
Selenium NMR has become a standard tool for scaling the π-accepting character of carbenes. Herein, w...
A new method for the assessment of the π-acceptor strength of N-heterocyclic carbenes is presented. ...
N-heterocyclic carbenes (NHCs) are common ancillary ligands in organometallic compounds that are use...
The electronic nature of the interaction of NHCs with metal centres is of interest when exploring th...
The electronic nature of the interaction of NHCs with metal centres is of interest when exploring th...
A series of novel low-valent organoselenium compounds stabilized by Se...N intramolecular interactio...
This dissertation involves the study and manipulation of molecular orbitals on ambiphilic molecules ...
A combined experimental/computational study of cooperativity between halogen-(XB) and hydrogen bondi...
The electronic nature of the interaction of NHCs with metal centres is of interest when exploring th...
Experimental Se-77 NMR parameters for 17 selenium-containing compounds have been determined by analy...
A series of novel low-valent organoselenium compounds stabilized by Se···N intramolec...
Nonbonded interactions involving selenium have been recognized for many years and are known to invol...
Selenium substituents which are disposed β to an electron deficient centre, such as a carbocation p-...
Selenium substituents which are disposed β to an electron deficient centre, such as a carbocation p-...
Various inorganic selenium-based compounds were analysed by Se-77 solid-state NMR, and a distinct di...