Add to ORKGA one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octabromo-meso-tris(2,6-dibromo-3,5-dimethoxyphenyl)corrole, a new bis-pocket metallocorrole. The Cu complex underwent smooth demetalation under reductive conditions, affording the free corrole ligand, which in turn could be readily complexed to MnIII and AuIII. A single-crystal X-ray structure was obtained for the MnIII complex
Although rather delicate on account of their propensity to undergo deiodination, β-octaiodoporphyrin...
On pyrrole! The pyrrole-based corrole ligands can offer an alternative to porphyrin systems. The man...
© 2015 World Scientific Publishing Company. After the definition of efficient synthetic routes for t...
A one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octa...
Bis-corroles have been prepared through a convergent synthesis using a copper-catalyzed azide–alkyne...
Presented herein is a study of the acid-induced demetalation of two sterically hindered copper corro...
Presented herein is a study of the acid-induced demetalation of two sterically hindered copper corro...
Different strategies for the demetalation of corrole complexes have been developed, using copper com...
The coordination chemistry of corrole is one of the most intriguing aspects of this contracted porph...
Although rather delicate on account of their propensity to undergo deiodination, β-octaiodoporphyrin...
The introduction of alkynyl groups at the β-pyrrolic positions of dibrominated corrole derivatives w...
The Rothemund condensation reaction of pyrrole and aldehydes is an extensively used route to meso-te...
Although rather delicate on account of their propensity to undergo deiodination, β-octaiodoporphyrin...
On pyrrole! The pyrrole-based corrole ligands can offer an alternative to porphyrin systems. The man...
© 2015 World Scientific Publishing Company. After the definition of efficient synthetic routes for t...
A one-pot protocol, effecting 14-fold bromination with elemental bromine, has afforded copper β-octa...
Bis-corroles have been prepared through a convergent synthesis using a copper-catalyzed azide–alkyne...
Presented herein is a study of the acid-induced demetalation of two sterically hindered copper corro...
Presented herein is a study of the acid-induced demetalation of two sterically hindered copper corro...
Different strategies for the demetalation of corrole complexes have been developed, using copper com...
The coordination chemistry of corrole is one of the most intriguing aspects of this contracted porph...
Although rather delicate on account of their propensity to undergo deiodination, β-octaiodoporphyrin...
The introduction of alkynyl groups at the β-pyrrolic positions of dibrominated corrole derivatives w...
The Rothemund condensation reaction of pyrrole and aldehydes is an extensively used route to meso-te...
Although rather delicate on account of their propensity to undergo deiodination, β-octaiodoporphyrin...
On pyrrole! The pyrrole-based corrole ligands can offer an alternative to porphyrin systems. The man...
© 2015 World Scientific Publishing Company. After the definition of efficient synthetic routes for t...