A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiazonium tetrafluoroborates is described. The reaction proceeds through visible-light mediated oxidative addition of aryldiazoniums, transmetalation of alkynyltrimethylsilanes and aryl-alkynyl reductive elimination. Exclusive selectivity for silyl-substituted alkynes is observed, with no reactivity observed for terminal alkynes
International audienceAlkylsilicates were engaged under photoredox/nickel dual catalysis conditions ...
2017-2018 > Academic research: refereed > Publication in refereed journal201805 bcrcVersion of Recor...
The merging of photoredox and transition-metal catalysis has become one of the most attractive appro...
A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiaz...
RSC: link from this PDF version to the published article on the Royal Society of Chemistry websiteA ...
Chapter 1. Photoredox Catalysis Unlocks Single-Electron Elementary Steps inTransition Metal Catalyze...
Chapter 1. Photoredox Catalysis Unlocks Single-Electron Elementary Steps inTransition Metal Catalyze...
A method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merge...
International audienceThe well-established oxidative addition-reductive elimination pathway is the m...
A room-temperature intramolecular oxy- and aminoarylation of alkenes with aryldiazonium salts has be...
Photoheterolysis of aryl halides substituted with electron-donating groups (EDGs) or aryl esters in ...
Photoheterolysis of aryl halides substituted with electron-donating groups (EDGs) or aryl esters in ...
A strategy for cross-electrophile coupling has been developed via the merger of photoredox and trans...
A gold-catalyzed C(sp3)-C(sp2) Suzuki-Miyaura coupling reaction facilitated by the ligand-enabled Au...
Here, we describe a photoredox-assisted catalytic system for the direct reductive coupling of two ca...
International audienceAlkylsilicates were engaged under photoredox/nickel dual catalysis conditions ...
2017-2018 > Academic research: refereed > Publication in refereed journal201805 bcrcVersion of Recor...
The merging of photoredox and transition-metal catalysis has become one of the most attractive appro...
A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiaz...
RSC: link from this PDF version to the published article on the Royal Society of Chemistry websiteA ...
Chapter 1. Photoredox Catalysis Unlocks Single-Electron Elementary Steps inTransition Metal Catalyze...
Chapter 1. Photoredox Catalysis Unlocks Single-Electron Elementary Steps inTransition Metal Catalyze...
A method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merge...
International audienceThe well-established oxidative addition-reductive elimination pathway is the m...
A room-temperature intramolecular oxy- and aminoarylation of alkenes with aryldiazonium salts has be...
Photoheterolysis of aryl halides substituted with electron-donating groups (EDGs) or aryl esters in ...
Photoheterolysis of aryl halides substituted with electron-donating groups (EDGs) or aryl esters in ...
A strategy for cross-electrophile coupling has been developed via the merger of photoredox and trans...
A gold-catalyzed C(sp3)-C(sp2) Suzuki-Miyaura coupling reaction facilitated by the ligand-enabled Au...
Here, we describe a photoredox-assisted catalytic system for the direct reductive coupling of two ca...
International audienceAlkylsilicates were engaged under photoredox/nickel dual catalysis conditions ...
2017-2018 > Academic research: refereed > Publication in refereed journal201805 bcrcVersion of Recor...
The merging of photoredox and transition-metal catalysis has become one of the most attractive appro...