Correlated electron phenomena in lanthanide and actinide materials are driven by a complex interplay between the f and d orbitals. In this study, aluminum K-edge x-ray absorption spectroscopy and density functional theory calculations are used to evaluate the electronic structure of the dialuminides, MAl2 (M = Ce, Sm, Eu, Yb, Lu, U, and Pu). The results show how the energy and occupancy of the 4f or 5f orbitals impacts mixing of Al 3p character into the 5d or 6d conduction bands, which has implications for understanding the magnetic and structural properties of correlated electron systems
Understanding how interactions between the f orbitals and ligand orbitals in lanthanide and actinide...
The electronic properties of actinide cations are of fundamental interest to describe intramolecular...
Based on the density functional theory and using GGA and GGA + so approximations, the electronic and...
Correlated electron phenomena in lanthanide and actinide materials are driven by a complex interplay...
Chapter 1:Polarized aluminum K-edge X-ray Absorption Spectroscopy (XAS) and first principle calculat...
Polarized aluminum K-edge X-ray absorption near edge structure (XANES) spectroscopy and first-princi...
We report a comparative study of the bulk electronic structure of two Al-based complex metallic allo...
The paramagnetic electronic structure calculations of the R3Al5O12 (R = Ce-Lu, the rare-earth elemen...
The behavior of the 5f electrons as the crucial factor in determining the electronic properties of m...
Evaluating the nature of chemical bonding for actinide elements represents one of the most important...
Previous magnetic, spectroscopic, and theoretical studies of cerocene, Ce(C8H8)2, have provided evid...
In recent years, collaborative studies that leverage experimental synthesis, spectroscopic character...
Polarized aluminum K-edge X-ray absorption near edge structure (XANES) spectroscopy and first-princi...
A comparative examination of the electronic interactions across a series of trimetallic actinide and...
The doping effect of aluminum arsenide (AlAs) with 3d (TM = V, Cr, and Mn) of transition metal impur...
Understanding how interactions between the f orbitals and ligand orbitals in lanthanide and actinide...
The electronic properties of actinide cations are of fundamental interest to describe intramolecular...
Based on the density functional theory and using GGA and GGA + so approximations, the electronic and...
Correlated electron phenomena in lanthanide and actinide materials are driven by a complex interplay...
Chapter 1:Polarized aluminum K-edge X-ray Absorption Spectroscopy (XAS) and first principle calculat...
Polarized aluminum K-edge X-ray absorption near edge structure (XANES) spectroscopy and first-princi...
We report a comparative study of the bulk electronic structure of two Al-based complex metallic allo...
The paramagnetic electronic structure calculations of the R3Al5O12 (R = Ce-Lu, the rare-earth elemen...
The behavior of the 5f electrons as the crucial factor in determining the electronic properties of m...
Evaluating the nature of chemical bonding for actinide elements represents one of the most important...
Previous magnetic, spectroscopic, and theoretical studies of cerocene, Ce(C8H8)2, have provided evid...
In recent years, collaborative studies that leverage experimental synthesis, spectroscopic character...
Polarized aluminum K-edge X-ray absorption near edge structure (XANES) spectroscopy and first-princi...
A comparative examination of the electronic interactions across a series of trimetallic actinide and...
The doping effect of aluminum arsenide (AlAs) with 3d (TM = V, Cr, and Mn) of transition metal impur...
Understanding how interactions between the f orbitals and ligand orbitals in lanthanide and actinide...
The electronic properties of actinide cations are of fundamental interest to describe intramolecular...
Based on the density functional theory and using GGA and GGA + so approximations, the electronic and...
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