Liquid organic hydrogen carriers such as alcohols and polyols are a high-capacity means of transporting and reversibly storing hydrogen that demands effective catalysts to drive the (de)hydrogenation reactions under mild conditions. We employed a combined theory/experiment approach to develop MOF-74 catalysts for alcohol dehydrogenation and examine the performance of the open metal sites (OMS), which have properties analogous to the active sites in high-performance single-site catalysts and homogeneous catalysts. Methanol dehydrogenation was used as a model reaction system for assessing the performance of five monometallic M-MOF-74 variants (M = Co, Cu, Mg, Mn, Ni). Co-MOF-74 and Ni-MOF-74 give the highest H2 productivity. However, Ni-MOF-7...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
Acceptorless dehydrogenation into carbonyls and molecular hydrogen is an attractive strategy to valo...
Includes bibliographical references (p. 40-44).The move away from a petroleum based economy requires...
Liquid organic hydrogen carriers such as alcohols and polyols are a high-capacity means of transport...
We demonstrate that metal-organic frameworks (MOFs) can catalyze hydrogenolysis of aryl ether bonds ...
Acceptorless dehydrogenation into carbonyls and molecular hydrogen is an attractive strategy to valo...
We demonstrate that metal–organic frameworks (MOFs) can catalyze hydrogenolysis of aryl ether bonds ...
Acceptorless dehydrogenation into carbonyls and molecular hydrogen is an attractive strategy to valo...
Acceptorless dehydrogenation into carbonyls and molecular hydrogen is an attractive strategy to valo...
To date, there has been no comprehensive attempt to perform and/or describe catalytic reactions in t...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
Acceptorless dehydrogenation into carbonyls and molecular hydrogen is an attractive strategy to valo...
Includes bibliographical references (p. 40-44).The move away from a petroleum based economy requires...
Liquid organic hydrogen carriers such as alcohols and polyols are a high-capacity means of transport...
We demonstrate that metal-organic frameworks (MOFs) can catalyze hydrogenolysis of aryl ether bonds ...
Acceptorless dehydrogenation into carbonyls and molecular hydrogen is an attractive strategy to valo...
We demonstrate that metal–organic frameworks (MOFs) can catalyze hydrogenolysis of aryl ether bonds ...
Acceptorless dehydrogenation into carbonyls and molecular hydrogen is an attractive strategy to valo...
Acceptorless dehydrogenation into carbonyls and molecular hydrogen is an attractive strategy to valo...
To date, there has been no comprehensive attempt to perform and/or describe catalytic reactions in t...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
International audienceAbstract Acceptorless dehydrogenation into carbonyls and molecular hydrogen is...
Acceptorless dehydrogenation into carbonyls and molecular hydrogen is an attractive strategy to valo...
Includes bibliographical references (p. 40-44).The move away from a petroleum based economy requires...