Syntes av porösa ramverksmaterial från förnybara utgångsämnen

Metal organic frameworks (MOFs) is a quite recently discovered porous material group which shows potential in many different areas. One of these areas is carbon capture; the framework structure of the porous materials allows gas molecules to adsorb to the surface of the pores. MOFs are conventionally synthesised at high temperatures and with hazardous solvents. The goal of this projectwas to synthesise highly porous MOFs at room temperature with water as the main solvent, using environmentally friendly and non-hazardous precursors. As well as the room temperature synthesis, conventional synthesis methods were used with the same precursors as comparison. The materials were characterised with X-ray diffraction, thermogravimetrical methods and IR-spectroscopy. To assess the porosity of the materials, gas adsorption evaluation was performed with CO2, N2, SF6, and CH4 at 20⁰C. In the end, three novel porous magnesium-based materials and one zirconium-based material were successfully synthesised. One of the magnesium-based materials showed a moderately high CO2 adsorption (2.38mmol/g), and could be synthesised at room temperature. The zirconium-based material showed a remarkably high selectivity (17.7) for SF6 over N2 and a high surface area (550m2/g