3,3-Dibromo-2-trifluoromethyl acrylic acid ethyl ester: a versatile platform for the stereoselective preparation of functionalized-α-trifluoromethyl α,β-unsaturated lactones and trifluoromethyl pyrazolinones

Switchable reactivity: the site-selective functionalization of trifluoromethyl-substituted pyrazoles

Schlosser, Manfred
Volle, Jean-Noel
Leroux, Frederic
Schenk, Kurt

March 2006

Modern organometallic methods enable the regioflexible conversion of simple heterocyclic starting ma...

Suzuki–Miyaura Micellar One-Pot Synthesis of Symmetrical and Unsymmetrical 4,7-Diaryl-5,6-difluoro-2,1,3-benzothiadiazole Luminescent Derivatives in Water and under Air

Alessandro Sanzone (3695092)
Adiel Calascibetta (6028538)
Erika Ghiglietti (6028541)
Chiara Ceriani (6028544)
Giuseppe Mattioli (1664212)
Sara Mattiello (3695089)
Mauro Sassi (1568323)
Luca Beverina (1934071)

November 2018

The Suzuki–Miyaura cross-coupling reaction of 4,7-dibromo-5,6-difluoro-2,1,3-benzothiadiazole with d...

Functionalized organotrifluoroborates: Synthesis and reactivity. I.Suzuki-Miyaura reactions of aryl- and heteroaryl trifluoroborates with aryl- and heteroaryl triflates. II. Oxidation of hydroxyl-containing trifluoroborates. III. Suzuki-Miyaura reactions of potassium trifluoroboratohomoenolates. IV. Development of a HRMS method for organotrifluoroborates

Petrillo, Daniel E

January 2008

Potassium organotrifluoroborates have emerged as extremely versatile reagents in synthesis. They exh...

3,3-Dibromo-2-trifluoromethyl acrylic acid ethyl ester: a versatile platform for the stereoselective preparation of functionalized-α-trifluoromethyl α,β-unsaturated lactones and trifluoromethyl pyrazolinones

Mizuta, Satoshi
Otaki, Hiroki
Kitamura, Kanami
Nishi, Kodai
Watanabe, Ken
Makau, Juliann Nzembi
Hashimoto, Ryo
Usui, Toshiya
Chiba, Kenya

December 2016

We herein describe a method for synthetic routes to multi-functionalized-α-trifluoromethyl α,β-unsat...

Suzuki-Miyuara cross-coupling reactions and methods development using organotrifluoroborates

Sandrock, Deidre L

January 2010

Organotrifluoroborates have emerged in the past decade as suitable nucleophilic partners for the Suz...

Synthesis of Conjugated Tri(hetero)aryl Derivatives Based on One-Pot Double Suzuki–Miyaura Couplings Using Bifunctional Dipotassium Phenylene-1,4- Bis(Trifluoroborate)

Salomone, A
Petrera, M
Coppi, D. I
PERNA, FILIPPO
Florio, S
CAPRIATI, Vito

January 2011

An efficient one-pot double Suzuki-Miyaura cross--coupling reaction between bifunctional phenylene-1...

Rapid Access to bi- and tri-functionalized Dibenzofurans and their Application in selective Suzuki-Miyaura Cross Coupling Reactions

Wern, Caroline
Ehrenreich, Christian
Joosten, Dominik
Vom Stein, Thorsten
Buchholz, Herwig
König, Burkhard

January 2018

Syntheses of 1,2-, 1,3-, 1,4-, 1,8-, 2,4-, 3,4-, 4,8-, 1,2,4-, 1,2,8- and 1,3,4-functionalized diben...

α,β-Disubstituted CF3-Enones as a Trifluoromethyl Building Block: Regioselective Preparation of Totally Substituted 3-CF3-Pyrazoles

Muzalevskiy V.M.
Sizova Z.A.
Panyushkin V.V.
Chertkov V.A.
Khrustalev V.N.
Nenajdenko V.G.

An efficient pathway toward a novel class of trifluoromethyl building blocks was elaborated. The rea...

Design, Synthesis and Suzuki-Miyaura Cross-Coupling Reactions of

January 2013

The Suzuki–Miyaura cross-coupling reaction is one of the most efficient methods to form new carbon-c...

α,β-Disubstituted CF3-Enones as a Trifluoromethyl Building Block: Regioselective Preparation of Totally Substituted 3-CF3-Pyrazoles

Muzalevskiy V.M.
Sizova Z.A.
Panyushkin V.V.
Chertkov V.A.
Nenajdenko V.G.
Khrustalev V.N.

An efficient pathway toward a novel class of trifluoromethyl building blocks was elaborated. The rea...

Palladium Catalyzed Suzuki-Miyaura Cross-Coupling of Secondary α-(Trifluoromethyl)benzyl Tosylates

Brambilla, M.
Tredwell, M.

September 2017

A palladium catalyzed C(sp3)-C(sp2) Suzuki-Miyaura cross-coupling of aryl boronic acids and α-(trifl...

Design, Synthesis and Suzuki-Miyaura Cross-Coupling Reactions of Potassium Organotrifluoroborates

Shin, Inji

January 2013

The Suzuki–Miyaura cross-coupling reaction is one of the most efficient methods to form new carbon-c...

Stereospecific Synthesis of Tri- and Tetrasubstituted α‑Fluoroacrylates by Mizoroki−Heck Reaction

Rousée, Kevin
Bouillon, J.-P.
Couve-Bonnaire, Samuel
Pannecoucke, Xavier

January 2016

International audienceLigand-free, efficient, palladium-catalyzed Mizoroki–Heck reaction between met...

Design, synthesis and Suzuki-Miyaura cross-coupling reactions of potassium organotrifluoroborates

Shin, Inji

January 2013

The Suzuki–Miyaura cross-coupling reaction is one of the most efficient methods to form new carbon-c...

From α-Bromomethylbutenolide to Fused Tri(Tetra) Cyclic Dihydrofurandiones through Barbier Reaction–Heck Arylation Sequence

Arbia Talbi

December 2017

A Barbier reaction–Heck arylation sequence from α-bromomethylbutenolide to fused tri and tetracyclic...

Switchable reactivity: the site-selective functionalization of trifluoromethyl-substituted pyrazoles

Schlosser, Manfred
Volle, Jean-Noel
Leroux, Frederic
Schenk, Kurt

March 2006

Modern organometallic methods enable the regioflexible conversion of simple heterocyclic starting ma...

Suzuki–Miyaura Micellar One-Pot Synthesis of Symmetrical and Unsymmetrical 4,7-Diaryl-5,6-difluoro-2,1,3-benzothiadiazole Luminescent Derivatives in Water and under Air

Alessandro Sanzone (3695092)
Adiel Calascibetta (6028538)
Erika Ghiglietti (6028541)
Chiara Ceriani (6028544)
Giuseppe Mattioli (1664212)
Sara Mattiello (3695089)
Mauro Sassi (1568323)
Luca Beverina (1934071)

November 2018

The Suzuki–Miyaura cross-coupling reaction of 4,7-dibromo-5,6-difluoro-2,1,3-benzothiadiazole with d...

Functionalized organotrifluoroborates: Synthesis and reactivity. I.Suzuki-Miyaura reactions of aryl- and heteroaryl trifluoroborates with aryl- and heteroaryl triflates. II. Oxidation of hydroxyl-containing trifluoroborates. III. Suzuki-Miyaura reactions of potassium trifluoroboratohomoenolates. IV. Development of a HRMS method for organotrifluoroborates

Petrillo, Daniel E

January 2008

Potassium organotrifluoroborates have emerged as extremely versatile reagents in synthesis. They exh...

3,3-Dibromo-2-trifluoromethyl acrylic acid ethyl ester: a versatile platform for the stereoselective preparation of functionalized-α-trifluoromethyl α,β-unsaturated lactones and trifluoromethyl pyrazolinones

Mizuta, Satoshi
Otaki, Hiroki
Kitamura, Kanami
Nishi, Kodai
Watanabe, Ken
Makau, Juliann Nzembi
Hashimoto, Ryo
Usui, Toshiya
Chiba, Kenya

December 2016

We herein describe a method for synthetic routes to multi-functionalized-α-trifluoromethyl α,β-unsat...

Suzuki-Miyuara cross-coupling reactions and methods development using organotrifluoroborates

Sandrock, Deidre L

January 2010

Organotrifluoroborates have emerged in the past decade as suitable nucleophilic partners for the Suz...

Synthesis of Conjugated Tri(hetero)aryl Derivatives Based on One-Pot Double Suzuki–Miyaura Couplings Using Bifunctional Dipotassium Phenylene-1,4- Bis(Trifluoroborate)

Salomone, A
Petrera, M
Coppi, D. I
PERNA, FILIPPO
Florio, S
CAPRIATI, Vito

January 2011

An efficient one-pot double Suzuki-Miyaura cross--coupling reaction between bifunctional phenylene-1...

Rapid Access to bi- and tri-functionalized Dibenzofurans and their Application in selective Suzuki-Miyaura Cross Coupling Reactions

Wern, Caroline
Ehrenreich, Christian
Joosten, Dominik
Vom Stein, Thorsten
Buchholz, Herwig
König, Burkhard

January 2018

Syntheses of 1,2-, 1,3-, 1,4-, 1,8-, 2,4-, 3,4-, 4,8-, 1,2,4-, 1,2,8- and 1,3,4-functionalized diben...

α,β-Disubstituted CF3-Enones as a Trifluoromethyl Building Block: Regioselective Preparation of Totally Substituted 3-CF3-Pyrazoles

Muzalevskiy V.M.
Sizova Z.A.
Panyushkin V.V.
Chertkov V.A.
Khrustalev V.N.
Nenajdenko V.G.

An efficient pathway toward a novel class of trifluoromethyl building blocks was elaborated. The rea...

Design, Synthesis and Suzuki-Miyaura Cross-Coupling Reactions of

January 2013

The Suzuki–Miyaura cross-coupling reaction is one of the most efficient methods to form new carbon-c...

α,β-Disubstituted CF3-Enones as a Trifluoromethyl Building Block: Regioselective Preparation of Totally Substituted 3-CF3-Pyrazoles

Muzalevskiy V.M.
Sizova Z.A.
Panyushkin V.V.
Chertkov V.A.
Nenajdenko V.G.
Khrustalev V.N.

An efficient pathway toward a novel class of trifluoromethyl building blocks was elaborated. The rea...

Palladium Catalyzed Suzuki-Miyaura Cross-Coupling of Secondary α-(Trifluoromethyl)benzyl Tosylates

Brambilla, M.
Tredwell, M.

September 2017

A palladium catalyzed C(sp3)-C(sp2) Suzuki-Miyaura cross-coupling of aryl boronic acids and α-(trifl...

Design, Synthesis and Suzuki-Miyaura Cross-Coupling Reactions of Potassium Organotrifluoroborates

Shin, Inji

January 2013

The Suzuki–Miyaura cross-coupling reaction is one of the most efficient methods to form new carbon-c...

Stereospecific Synthesis of Tri- and Tetrasubstituted α‑Fluoroacrylates by Mizoroki−Heck Reaction

Rousée, Kevin
Bouillon, J.-P.
Couve-Bonnaire, Samuel
Pannecoucke, Xavier

January 2016

International audienceLigand-free, efficient, palladium-catalyzed Mizoroki–Heck reaction between met...

Design, synthesis and Suzuki-Miyaura cross-coupling reactions of potassium organotrifluoroborates

Shin, Inji

January 2013

The Suzuki–Miyaura cross-coupling reaction is one of the most efficient methods to form new carbon-c...

From α-Bromomethylbutenolide to Fused Tri(Tetra) Cyclic Dihydrofurandiones through Barbier Reaction–Heck Arylation Sequence

Arbia Talbi

December 2017

A Barbier reaction–Heck arylation sequence from α-bromomethylbutenolide to fused tri and tetracyclic...

Switchable reactivity: the site-selective functionalization of trifluoromethyl-substituted pyrazoles

Schlosser, Manfred
Volle, Jean-Noel
Leroux, Frederic
Schenk, Kurt

March 2006

Modern organometallic methods enable the regioflexible conversion of simple heterocyclic starting ma...

Suzuki–Miyaura Micellar One-Pot Synthesis of Symmetrical and Unsymmetrical 4,7-Diaryl-5,6-difluoro-2,1,3-benzothiadiazole Luminescent Derivatives in Water and under Air

Alessandro Sanzone (3695092)
Adiel Calascibetta (6028538)
Erika Ghiglietti (6028541)
Chiara Ceriani (6028544)
Giuseppe Mattioli (1664212)
Sara Mattiello (3695089)
Mauro Sassi (1568323)
Luca Beverina (1934071)

November 2018

The Suzuki–Miyaura cross-coupling reaction of 4,7-dibromo-5,6-difluoro-2,1,3-benzothiadiazole with d...

Functionalized organotrifluoroborates: Synthesis and reactivity. I.Suzuki-Miyaura reactions of aryl- and heteroaryl trifluoroborates with aryl- and heteroaryl triflates. II. Oxidation of hydroxyl-containing trifluoroborates. III. Suzuki-Miyaura reactions of potassium trifluoroboratohomoenolates. IV. Development of a HRMS method for organotrifluoroborates

Petrillo, Daniel E

January 2008

Potassium organotrifluoroborates have emerged as extremely versatile reagents in synthesis. They exh...

3,3-Dibromo-2-trifluoromethyl acrylic acid ethyl ester: a versatile platform for the stereoselective preparation of functionalized-α-trifluoromethyl α,β-unsaturated lactones and trifluoromethyl pyrazolinones

Abstract

Extracted data

3,3-Dibromo-2-trifluoromethyl acrylic acid ethyl ester: a versatile platform for the stereoselective preparation of functionalized-α-trifluoromethyl α,β-unsaturated lactones and trifluoromethyl pyrazolinones

Abstract

Extracted data

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