The structure and reactivity of gas phase ionic clusters were studied using molecular beam mass-spectrometry, vibrational predissociation spectroscopy and Monte Carlo simulation. Cluster ions of the form M$\sp+$(S)$\sb{\rm N}$, M = Cs, Na and S = CH$\sb3$OH, NH$\sb3$, CH$\sb3$NH$\sb2$, (CH$\sb3)\sb2$CO and (CH$\sb3)\sb2$SO were prepared in the source chamber of continuous molecular beam apparatus. Quasi-stable cluster ions were mass selected with a quadrupole mass filter and size selective infrared spectroscopy was carried out on size selected clusters with as many as thirty solvent molecules. Vibrational predissociation of the clusters using a line tunable CO$\sb2$ laser was detected using the beam depletion method. By comparing the infrar...
Author Institution: School of Chemical Sciences, University of Illinois.The combination of a thermio...
Author Institution: School of Chemical Sciences, University of Illinois.The combination of a thermio...
Author Institution: School of Chemical Sciences, University of Illinois at UrbanaThe combination of ...
1.Introduction. Electrons and metal ions in fluids play important roles in many aspects of chemlca...
The solvation of the alkali ions Na$\sp{+}$ and Cs$\sp{+}$ by methanol has been investigated by gas-...
Author Institution: School of Chemical Sciences, University of Illinois at Urbana-ChampaignAmmonia s...
Author Institution: School of Chemical Sciences, University of Illinois at Urbana-ChampaignAmmonia s...
Author Institution: School of Chemical Sciences, University of IllinoisVibrational predissoclation s...
Solvated transition metal solvent cluster ions were generated by electrospray ionization and their s...
Solvated transition metal solvent cluster ions were generated by electrospray ionization and their s...
Solvated transition metal solvent cluster ions were generated by electrospray ionization and their s...
The central goal of the present thesis is the structural characterization of metal oxide clusters in...
$^{1}$ D.W. Michael and J.M. Lisy, J. Chem. Phys. 85, 2528 (1986).Author Institution: Department of ...
Solvated transition metal solvent cluster ions were generated by electrospray ionization and their s...
$^{1}$ D.W. Michael and J.M. Lisy, J. Chem. Phys. 85, 2528 (1986).Author Institution: Department of ...
Author Institution: School of Chemical Sciences, University of Illinois.The combination of a thermio...
Author Institution: School of Chemical Sciences, University of Illinois.The combination of a thermio...
Author Institution: School of Chemical Sciences, University of Illinois at UrbanaThe combination of ...
1.Introduction. Electrons and metal ions in fluids play important roles in many aspects of chemlca...
The solvation of the alkali ions Na$\sp{+}$ and Cs$\sp{+}$ by methanol has been investigated by gas-...
Author Institution: School of Chemical Sciences, University of Illinois at Urbana-ChampaignAmmonia s...
Author Institution: School of Chemical Sciences, University of Illinois at Urbana-ChampaignAmmonia s...
Author Institution: School of Chemical Sciences, University of IllinoisVibrational predissoclation s...
Solvated transition metal solvent cluster ions were generated by electrospray ionization and their s...
Solvated transition metal solvent cluster ions were generated by electrospray ionization and their s...
Solvated transition metal solvent cluster ions were generated by electrospray ionization and their s...
The central goal of the present thesis is the structural characterization of metal oxide clusters in...
$^{1}$ D.W. Michael and J.M. Lisy, J. Chem. Phys. 85, 2528 (1986).Author Institution: Department of ...
Solvated transition metal solvent cluster ions were generated by electrospray ionization and their s...
$^{1}$ D.W. Michael and J.M. Lisy, J. Chem. Phys. 85, 2528 (1986).Author Institution: Department of ...
Author Institution: School of Chemical Sciences, University of Illinois.The combination of a thermio...
Author Institution: School of Chemical Sciences, University of Illinois.The combination of a thermio...
Author Institution: School of Chemical Sciences, University of Illinois at UrbanaThe combination of ...