International audienceAn efficient, practical, and industrially relevant procedure for the production of polymer materials, in which a part of the oil-derived polyolefins has been replaced by a renewable, biodegradable, and biocompatible poly(lactide) block, is presented. Binary catalytic systems combining innocuous metals (yttrium, zinc, magnesium, or calcium) and bifunctional alcohols (acting as transfer agents) were developed to promote the immortal ring-opening polymerization of lactide directly in styrene. Up to 20 000 equivalents of lactide were polymerized (metal catalyst loading of 50-100 ppm) in a controlled fashion in the presence of 10-100 equivalents of a double-headed transfer agent to give as many end-functionalized poly(lacti...
The successful achievement of stereospecific metal catalyzed styrene polymn. using Ziegler Natta cat...
The successful achievement of stereospecific metal catalyzed styrene polymn. using Ziegler Natta cat...
The successful achievement of stereospecific metal catalyzed styrene polymn. using Ziegler Natta cat...
Poly(L-Lactide) is one of the most promising bio-resourced and bio-degradable polymers and may const...
International audienceNovel zinc(II) and cobalt(II) complexes containing tripodal mono(phenolate) li...
Selective transformation of carbon dioxide and epoxides into degradable polycarbonates (CO<sub>2</su...
International audienceNovel zinc(II) and cobalt(II) complexes containing tripodal mono(phenolate) li...
International audiencePoly(L-lactide) (PLLA) is often regarded as tough and brittle while poly(1,3-t...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
International audienceCopolymerization of L-LA and TMC has been achieved with binary systems, associ...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
In the presence of a small molecular protic initiator, immortal ring-opening polymerization (ROP) of...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
The successful achievement of stereospecific metal catalyzed styrene polymn. using Ziegler Natta cat...
The successful achievement of stereospecific metal catalyzed styrene polymn. using Ziegler Natta cat...
The successful achievement of stereospecific metal catalyzed styrene polymn. using Ziegler Natta cat...
Poly(L-Lactide) is one of the most promising bio-resourced and bio-degradable polymers and may const...
International audienceNovel zinc(II) and cobalt(II) complexes containing tripodal mono(phenolate) li...
Selective transformation of carbon dioxide and epoxides into degradable polycarbonates (CO<sub>2</su...
International audienceNovel zinc(II) and cobalt(II) complexes containing tripodal mono(phenolate) li...
International audiencePoly(L-lactide) (PLLA) is often regarded as tough and brittle while poly(1,3-t...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
International audienceCopolymerization of L-LA and TMC has been achieved with binary systems, associ...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
In the presence of a small molecular protic initiator, immortal ring-opening polymerization (ROP) of...
Poly(lactic acid) (PLA) is one of the best candidates as a sustainable plastic material for a circul...
The successful achievement of stereospecific metal catalyzed styrene polymn. using Ziegler Natta cat...
The successful achievement of stereospecific metal catalyzed styrene polymn. using Ziegler Natta cat...
The successful achievement of stereospecific metal catalyzed styrene polymn. using Ziegler Natta cat...