Add to ORKGMicrocrystalline substances of the composition [MgX12Lg]X2, M = Nb, Ta, X = Cl, Br, L = NH3, CH3CN, C5H5N, were prepared by the reaction of ethanolic solutions of [MgX12(C2H5OH)6]X2 with ammonia gas or simply by dissolving these clusters in acetonitrile or pyridine. The spectral data point to the occupancy of all octahedral coordination sites by nitrogen donor ligands
The title compound bis(benzothiazolium) dodeca-μ-chlorido-hexachlorido-octahedro-hexaniobium(12 Nb—N...
Diamino derivatives of niobium(l) and tantalum(l) of general formula MX(CO)4(NN), MNb, Ta; XCl, 1; N...
Early transition metal derivatives with N-donors have attracted interest as precursors of nitrides, ...
Microcrystalline substances of the composition [MgX12Lg]X2, M = Nb, Ta, X = Cl, Br, L = NH3, CH3CN, ...
Synthetic procedures providing straightforward access to the whole family of Nb and Ta halide cluste...
Reaction of [NbCl3(TMEDA)]2 with LDA in a stoichiometric ratio of 1:3 Nb/Lithium amide, resulted in ...
Niobium and tantalum compounds lived for long time in the shadow of metal complexes of group 4, prob...
Typescript (photocopy).A new entry into the area of low valent niobium and tantalum complexes contai...
The 1 : 1 molar reactions of niobium and tantalum pentahalides with the monodentate NHC ligand 1,3-b...
The reactivity of NbCl5, NbF5 and TaCl5 with a selection of commercial imines was investigated for t...
Five niobium cluster compounds of the AI2[Nb6Cl18] type (AI = organic cation: [nPr4N]+, [nBu4N]+, [B...
The metal halides of Group 5 MX5 (M = Nb, Ta; X = F, Cl, Br) react with ketones and acetylacetones a...
International audienceThis review summarizes the development of the rich crystal and bonding chemist...
An equilateral Nb3 triangle the edges of which are spanned by a BS4 tetrahedron and bridged by sulfi...
The chemistry of niobium and tantalum pentahalides, MX(5), with oxygen compounds is reviewed herein....
The title compound bis(benzothiazolium) dodeca-μ-chlorido-hexachlorido-octahedro-hexaniobium(12 Nb—N...
Diamino derivatives of niobium(l) and tantalum(l) of general formula MX(CO)4(NN), MNb, Ta; XCl, 1; N...
Early transition metal derivatives with N-donors have attracted interest as precursors of nitrides, ...
Microcrystalline substances of the composition [MgX12Lg]X2, M = Nb, Ta, X = Cl, Br, L = NH3, CH3CN, ...
Synthetic procedures providing straightforward access to the whole family of Nb and Ta halide cluste...
Reaction of [NbCl3(TMEDA)]2 with LDA in a stoichiometric ratio of 1:3 Nb/Lithium amide, resulted in ...
Niobium and tantalum compounds lived for long time in the shadow of metal complexes of group 4, prob...
Typescript (photocopy).A new entry into the area of low valent niobium and tantalum complexes contai...
The 1 : 1 molar reactions of niobium and tantalum pentahalides with the monodentate NHC ligand 1,3-b...
The reactivity of NbCl5, NbF5 and TaCl5 with a selection of commercial imines was investigated for t...
Five niobium cluster compounds of the AI2[Nb6Cl18] type (AI = organic cation: [nPr4N]+, [nBu4N]+, [B...
The metal halides of Group 5 MX5 (M = Nb, Ta; X = F, Cl, Br) react with ketones and acetylacetones a...
International audienceThis review summarizes the development of the rich crystal and bonding chemist...
An equilateral Nb3 triangle the edges of which are spanned by a BS4 tetrahedron and bridged by sulfi...
The chemistry of niobium and tantalum pentahalides, MX(5), with oxygen compounds is reviewed herein....
The title compound bis(benzothiazolium) dodeca-μ-chlorido-hexachlorido-octahedro-hexaniobium(12 Nb—N...
Diamino derivatives of niobium(l) and tantalum(l) of general formula MX(CO)4(NN), MNb, Ta; XCl, 1; N...
Early transition metal derivatives with N-donors have attracted interest as precursors of nitrides, ...