Add to ORKGSolvolysis rates of tertiary chlorides 1-6 and their hexadeuterated analogs 1-dg-6-đe were measured in ethanol (q> = 80%) and 2,2,2- trifluoroethanol (w = 97%). The (5-deuterium KIE calculated showed that chloride 1 solvolyzes with n-participation of the methoxy group in the rate determining step, while chloride 2 solvolyzes mainly by way of a kc process. Based on the reduced P-deuterium isotope effect, it was also concluded that in the solvolysis of chloride 5 7t-electrons take part in the rate-determining step
The specific rates of solvolysis of benzyl fluoroformate have been measured inseveral hydroxylic sol...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 °C in 22 p...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 degrees C ...
Solvolysis rates of tertiary chlorides 1-6 and their hexadeuterated analogs 1-dg-6-đe were measured ...
Solvolysis rates of tertiary chlorides 1-6 and their hexadeuterated analogs 1-dg-6-đe were measured ...
Solvolysis rates of tertiary chlorides 1-6 and their hexadeuterated analogs 1-dg-6-đe were measured ...
Despite numerous comparisons of the reactivities of saturated organic halides toward nucleophilic re...
Despite numerous comparisons of the reactivities of saturated organic halides toward nucleophilic re...
The solvolysis rate constants of 3,4- (1) and 3,5-dimethoxybenzoyl (2) chlorides were measured in va...
The introduction of methoxy groups into the 3- and 5-positions of 4-methoxybenzoyl chloride leads to...
Primary aind tertiary dimethylallyl chlorides deuterated at either the alpha or gamma pos~tion were ...
Primary aind tertiary dimethylallyl chlorides deuterated at either the alpha or gamma pos~tion were ...
The ortho-effect of substituents upon the kinetics of reactions taking place at a reaction center at...
The specific rates of solvolysis of benzyl fluoroformate have been measured inseveral hydroxylic sol...
Abstract: The specific rates of solvolysis of benzyl fluoroformate have been measured in several hyd...
The specific rates of solvolysis of benzyl fluoroformate have been measured inseveral hydroxylic sol...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 °C in 22 p...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 degrees C ...
Solvolysis rates of tertiary chlorides 1-6 and their hexadeuterated analogs 1-dg-6-đe were measured ...
Solvolysis rates of tertiary chlorides 1-6 and their hexadeuterated analogs 1-dg-6-đe were measured ...
Solvolysis rates of tertiary chlorides 1-6 and their hexadeuterated analogs 1-dg-6-đe were measured ...
Despite numerous comparisons of the reactivities of saturated organic halides toward nucleophilic re...
Despite numerous comparisons of the reactivities of saturated organic halides toward nucleophilic re...
The solvolysis rate constants of 3,4- (1) and 3,5-dimethoxybenzoyl (2) chlorides were measured in va...
The introduction of methoxy groups into the 3- and 5-positions of 4-methoxybenzoyl chloride leads to...
Primary aind tertiary dimethylallyl chlorides deuterated at either the alpha or gamma pos~tion were ...
Primary aind tertiary dimethylallyl chlorides deuterated at either the alpha or gamma pos~tion were ...
The ortho-effect of substituents upon the kinetics of reactions taking place at a reaction center at...
The specific rates of solvolysis of benzyl fluoroformate have been measured inseveral hydroxylic sol...
Abstract: The specific rates of solvolysis of benzyl fluoroformate have been measured in several hyd...
The specific rates of solvolysis of benzyl fluoroformate have been measured inseveral hydroxylic sol...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 °C in 22 p...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 degrees C ...