The synthesis and characterisation of three palladium complexes, involved in the homogeneous catalysis towards the CO-olefins co-and ter-polymerisation reactions, are reported. The [Pd (dpk⋅CH3OH) (CF3CO2)2] (1), (dpk = di(2-pyridyl) ketone) and [Pd (dppp)(bipy)] [B(C6F5)4]2 (2), (bipy = 2,2’-bipyridine, dppp = 1,3-bis(diphenylphosphino)propane) compounds are examples of a neutral complex and of a dicationic mixed-ligands one, respectively. The catalytic activity of type 2 complexes was reported to be strongly dependent on the nature of the anion, and the tetra(perfluorophenyl) borate salt represents the best choice to date for the CO/aliphatic olefins copolymerisation. In both structures, the metal has a square planar coordination and...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthrolines (3-R-phen) to pal...
During the last decade there has been increased interest in the development of homogeneous catalytic...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthroline (3-R-phen) to pall...
The synthesis and characterisation of three palladium complexes, involved in the homogeneous catalys...
In this thesis, the synthesis of various P,N-ligands is reported. The ligands contain a C3-bridge th...
A series of Pd-complexes containing nonsymmetrical bis(aryl-imino)acenaphthene (Ar-BIAN) ligands, ch...
Polyolefins form a highly important class of materials, with a wide range of applications, which are...
The catalytic behavior of dicationic bis-chelated PdII complexes, [Pd(N-N)2][PF6]2, in the CO/ethyle...
The catalytic behavior of dicationic bis-chelated PdII complexes, [Pd(N-N)2][PF6]2, in the CO/ethyle...
Polyolefins form a highly important class of materials, with a wide range of applications, which are...
The catalytic behavior of dicationic bis-chelated PdII complexes, [Pd(N-N)2][PF6]2, in the CO/ethyle...
The catalytic behavior of dicationic bis-chelated PdII complexes, [Pd(NN)2][PF6]2, in the CO/ethylen...
A series of Pd-complexes containing nonsymmetrical bis(aryl-imino)acenaphthene (Ar-BIAN) ligands, ch...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthrolines (3-R-phen) to pal...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthrolines (3-R-phen) to pal...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthrolines (3-R-phen) to pal...
During the last decade there has been increased interest in the development of homogeneous catalytic...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthroline (3-R-phen) to pall...
The synthesis and characterisation of three palladium complexes, involved in the homogeneous catalys...
In this thesis, the synthesis of various P,N-ligands is reported. The ligands contain a C3-bridge th...
A series of Pd-complexes containing nonsymmetrical bis(aryl-imino)acenaphthene (Ar-BIAN) ligands, ch...
Polyolefins form a highly important class of materials, with a wide range of applications, which are...
The catalytic behavior of dicationic bis-chelated PdII complexes, [Pd(N-N)2][PF6]2, in the CO/ethyle...
The catalytic behavior of dicationic bis-chelated PdII complexes, [Pd(N-N)2][PF6]2, in the CO/ethyle...
Polyolefins form a highly important class of materials, with a wide range of applications, which are...
The catalytic behavior of dicationic bis-chelated PdII complexes, [Pd(N-N)2][PF6]2, in the CO/ethyle...
The catalytic behavior of dicationic bis-chelated PdII complexes, [Pd(NN)2][PF6]2, in the CO/ethylen...
A series of Pd-complexes containing nonsymmetrical bis(aryl-imino)acenaphthene (Ar-BIAN) ligands, ch...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthrolines (3-R-phen) to pal...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthrolines (3-R-phen) to pal...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthrolines (3-R-phen) to pal...
During the last decade there has been increased interest in the development of homogeneous catalytic...
The coordination chemistry of a series of 3-alkyl-substituted-1,10-phenanthroline (3-R-phen) to pall...