First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH:CH-py)2·2CH3CN, M = CoII, MnII.

Gavrilenko, Konstantin S.
Le Gal, Yann
Cador, Olivier
Golhen, Stéphane
Ouahab, Lahcene

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Publication date

January 2007

DOI

10.1039/B613191C

Publisher

Royal Society of Chemistry (RSC)

Abstract

International audienceThe first paramagnetic homo- and hetero-metallic trinuclear complexes, [Co2M(PhCOO)6(L)2]·2MeCN \M = Co, Mn; L = 4-[2-(tetrathiafulvalenyl)ethenyl]pyridine\ with redox active ligands derived from TTF were synthesized and structurally characterized. The central metal ion has an octahedral coordination sphere while the outer CoII ions are in a distorted bipyramidal surrounding, bearing TTF-ligands. The magnetic properties show antiferromagnetic coupling leading to a magnetic ground state

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First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH:CH-py)2·2CH3CN, M = CoII, MnII.

Abstract

Extracted data

First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH:CH-py)2·2CH3CN, M = CoII, MnII.

Abstract

Extracted data

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