This work contributes to establish the development of an early specific effect of chloride ions in defect-free coated metals leading to the heterogeneous swelling at the metal-polymer interface. Frequency-dependent alternating-current scanning electrochemical microscopy (AC-SECM) was successfully applied to visualize spatially-resolved differences in the topography of the coated sample, thus allowing direct evidence of chloride ion permeation through the polymer matrix simultaneous to water uptake to be obtained. The implications of this finding are particularly relevant towards the development of a new mechanistic model for blister initiation in coated metals
The suitability of frequency-dependent alternating-current scanning electrochemical microscopy (4D A...
Eventual limitations in the applicability of the SECM in the SG-TC mode to in situ monitor electroch...
This paper describes methods to study the initiation and formation of localized corrosion pits on st...
Alternating-current scanning electrochemical microscopy (AC-SECM) is employed to characterize the ea...
Negative-feedback scanning electrochemical microscopy (SECM) is successfully applied to visualize sp...
Scanning electrochemical microscopy has been employed to obtain spatially-resolved information regar...
The effect of oxygen content on the corrosion reactions inside a holiday in a polymer-coated metal s...
The local distribution of anodic and cathodic sites in a corroding cut edge using the scanning elect...
The local distribution of anodic and cathodic sites in a corroding cut edge using the scanning elect...
Alternating current scanning electrochemical microscopy (AC-SECM) is used to investigate the inhibit...
Application of scanning vibrating electrode technique (SVET) for corrosion studies of organic coati...
Spatially resolved information on corrosion reactions operating at the cut edges of coated metals ca...
Coil coated steel sheets immersed in 1 mM NaCl solutions adjusted at both acidic and alkaline pH con...
A new method for the investigation of the inhibition efficiency against corrosion by organic films a...
Aluminium alloy AA2024-T3 surfaces have been characterised by using a new microelectrochemical techn...
The suitability of frequency-dependent alternating-current scanning electrochemical microscopy (4D A...
Eventual limitations in the applicability of the SECM in the SG-TC mode to in situ monitor electroch...
This paper describes methods to study the initiation and formation of localized corrosion pits on st...
Alternating-current scanning electrochemical microscopy (AC-SECM) is employed to characterize the ea...
Negative-feedback scanning electrochemical microscopy (SECM) is successfully applied to visualize sp...
Scanning electrochemical microscopy has been employed to obtain spatially-resolved information regar...
The effect of oxygen content on the corrosion reactions inside a holiday in a polymer-coated metal s...
The local distribution of anodic and cathodic sites in a corroding cut edge using the scanning elect...
The local distribution of anodic and cathodic sites in a corroding cut edge using the scanning elect...
Alternating current scanning electrochemical microscopy (AC-SECM) is used to investigate the inhibit...
Application of scanning vibrating electrode technique (SVET) for corrosion studies of organic coati...
Spatially resolved information on corrosion reactions operating at the cut edges of coated metals ca...
Coil coated steel sheets immersed in 1 mM NaCl solutions adjusted at both acidic and alkaline pH con...
A new method for the investigation of the inhibition efficiency against corrosion by organic films a...
Aluminium alloy AA2024-T3 surfaces have been characterised by using a new microelectrochemical techn...
The suitability of frequency-dependent alternating-current scanning electrochemical microscopy (4D A...
Eventual limitations in the applicability of the SECM in the SG-TC mode to in situ monitor electroch...
This paper describes methods to study the initiation and formation of localized corrosion pits on st...