The electrochemical behavior of the binuclear platinum(III-III) complexes [Pt-2(C4H3N2S)(4)X-2] (C4H3N2S- = pyrimidine-2-thionate; X- = Cl--,Cl- Br--,Br- I-) have been studied by cyclic voltammetry and insitu spectroelectrochemistry in an acetonitrile-tetrabutylammonium tetrafluoroborate solventelectrolyte couple. An irreversible metal based reduction appears during the cathodic scan for each of the three complexes. The changes in UV-Vis spectra observed in-situ during the reductive electrolysis indicate that all three complexes give the same product, [Pt-2(C4H3N2S)(4)], with a Pt(II)-Pt(II) system. The changes in the reduction potentials of the complexes on changing the axial ligands are interpreted by the changes in the energy of the LUMO...
η3-Allyl complexes of the type [M(η3-allyl)(L2)]+ (M Pd; allyl = 1-MeC3H4; L2 = 1,5-C8H12, 2MeCN; al...
Characterization of the anticancer active compound trans-[Pt{(p-BrCF)NCHCHNEt}Cl(py)] is described a...
The electrochemical behaviour of Na(Et2NCS2) and M(Et2NCS2)(2) (M = NI(II), Pd(II) and Pt(II): Et2NC...
The voltammetric behaviour of cis-[Pt(PEt3)2(YC6H4)2] complexes in acetonitrile has been investigate...
A series of cyclometallated platinum(II) species with N-N-C ligands (N-N-C = ortho-C-deprotonated fo...
The cathodic reduction of the complexes [LPtCl] and [LPtL\u2032] (BF4) [HL \ue5fb 6-(1-methylbenzyl)...
The electrochemical behaviour of palladium(II), ruthenium(III), rhodium(III), osmium(IV), iridium(IV...
Reaction of 2-Li-4-MeC6H3AsPh2 with [PtCl2(SEt2)2] gives two isomeric dinuclear platinum(II) complex...
In dioxane and acetonitile solutions N-(thio)phosphorylated thiobenzamide and thioacetamide form sta...
The electrochemical behaviour of a series of cationic platinum(II) isocyanide complexes has been stu...
trans- [Pt(MeCN)(PPh3)2(2-thienyl)]BF4 (1) serves as a convenient precursor to bifunctional mononucl...
Characterization of the anticancer active compound trans-[PtII{(p-BrC6F4)NCH2CH2NEt2}Cl(py)] is desc...
Characterization of the anticancer active compound trans-[PtII{(p-BrC6F4)NCH2CH2NEt2}Cl(py)] is desc...
Electrochemical and spectrochemical behaviors of Ru(II) complexes with αα´-bipyridine and o-phenanth...
Electrochemical behaviours of Os (II)-αα'-bipyridine, Os (II)-o-phenanthroline, and Ru (Il)-αα' bipy...
η3-Allyl complexes of the type [M(η3-allyl)(L2)]+ (M Pd; allyl = 1-MeC3H4; L2 = 1,5-C8H12, 2MeCN; al...
Characterization of the anticancer active compound trans-[Pt{(p-BrCF)NCHCHNEt}Cl(py)] is described a...
The electrochemical behaviour of Na(Et2NCS2) and M(Et2NCS2)(2) (M = NI(II), Pd(II) and Pt(II): Et2NC...
The voltammetric behaviour of cis-[Pt(PEt3)2(YC6H4)2] complexes in acetonitrile has been investigate...
A series of cyclometallated platinum(II) species with N-N-C ligands (N-N-C = ortho-C-deprotonated fo...
The cathodic reduction of the complexes [LPtCl] and [LPtL\u2032] (BF4) [HL \ue5fb 6-(1-methylbenzyl)...
The electrochemical behaviour of palladium(II), ruthenium(III), rhodium(III), osmium(IV), iridium(IV...
Reaction of 2-Li-4-MeC6H3AsPh2 with [PtCl2(SEt2)2] gives two isomeric dinuclear platinum(II) complex...
In dioxane and acetonitile solutions N-(thio)phosphorylated thiobenzamide and thioacetamide form sta...
The electrochemical behaviour of a series of cationic platinum(II) isocyanide complexes has been stu...
trans- [Pt(MeCN)(PPh3)2(2-thienyl)]BF4 (1) serves as a convenient precursor to bifunctional mononucl...
Characterization of the anticancer active compound trans-[PtII{(p-BrC6F4)NCH2CH2NEt2}Cl(py)] is desc...
Characterization of the anticancer active compound trans-[PtII{(p-BrC6F4)NCH2CH2NEt2}Cl(py)] is desc...
Electrochemical and spectrochemical behaviors of Ru(II) complexes with αα´-bipyridine and o-phenanth...
Electrochemical behaviours of Os (II)-αα'-bipyridine, Os (II)-o-phenanthroline, and Ru (Il)-αα' bipy...
η3-Allyl complexes of the type [M(η3-allyl)(L2)]+ (M Pd; allyl = 1-MeC3H4; L2 = 1,5-C8H12, 2MeCN; al...
Characterization of the anticancer active compound trans-[Pt{(p-BrCF)NCHCHNEt}Cl(py)] is described a...
The electrochemical behaviour of Na(Et2NCS2) and M(Et2NCS2)(2) (M = NI(II), Pd(II) and Pt(II): Et2NC...