Polarized SERS on linear arrays of silver half-shells: SERS re-radiation modulated by local density of optical states

This work investigates polarization effects in surface-enhanced Raman scattering (SERS) on a particular kind of hybrid colloidal plasmonic-photonic crystal consisting in linear arrays of polystyrene colloids coated by a silver film forming caps (half-shells). The polarization of Raman scattering of adsorbed molecules is found to be imposed by the linear morphology of the plasmonic nanostructures, independent of the incident polarization. Specifically, it is demonstrated that the electric field component parallel to the linear plasmonic nanostructures brings the main contribution to the SERS enhancement for both parallel and perpendicular excitation. The stronger plasmon resonance, polarized along the chain of metal half-shells, is the one that determines the polarization of the SERS scattering, even if this resonance is not directly excited by the incident laser, but onlyre-radiated photons couple to it. ...