Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length

King-Him Yim
Chi-Tung Yeung
Michael R. Probert
Wesley Ting Kwok Chan
Lewis E. Mackenzie
Robert Pal
Wing-Tak Wong
Ga-Lai Law

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Publication date

August 2021

DOI

10.1038/s42004-021-00553-8

Publisher

Springer Science and Business Media LLC

Journal

Communications Chemistry

Abstract

Lanthanide-based supramolecular complexes have labile and hard-topredict chemical structures. Here the authors show controlled formation of either helicates or tetrahedron shaped cages based on the interplay between the metal ionic radius and the ligand composition

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Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length

Abstract

Extracted data

Helicate-to-tetrahedron transformation of chiral lanthanide supramolecular complexes induced by ionic radii effect and linker length

Abstract

Extracted data

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