Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydroxynaphthalene‐2,6‐dicarboxylic acid and divalent cations (M=Mn, Mg, Ni, Co) are shown to be isoreticular to the CPO‐27 (MOF‐74) materials. Desolvated CPO‐54‐Mn contains a very high concentration of open metal sites, which has a pronounced effect on the gas adsorption of N2, H2, CO2 and CO. Initial isosteric heats of adsorption are significantly higher than for MOFs without open metal sites and are slightly higher than for CPO‐27. The plateau of high heat of adsorption decreases earlier in CPO‐54‐Mn as a function of loading per mole than in CPO‐27‐Mn. Cluster and periodic density functional theory based calculations of the adsorbate structures ...
Metal–organic frameworks have emerged as a class of porous materials with structures that can be def...
Sem informaçãoThe synthesis of stable porous materials with appropriate pore size and shape for desi...
Metal–organic frameworks have emerged as a class of porous materials with structures that can be def...
Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydrox...
Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydrox...
Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydrox...
Metal-organic frameworks are a new class of porous materials that have potential applications in gas...
By using three rigid diisophthalate organic linkers incorporating different numbers and orientations...
Despite their having much greater potential for compositional and structural diversity, heterometall...
The work herein describes progress toward designing, synthesizing, and characterizing new metal–orga...
The work herein describes progress toward designing, synthesizing, and characterizing new metal–orga...
Two metal–organic framework materials, MFM-130 and MFM-131 (MFM = Manchester Framework Material), ha...
Two metal–organic framework materials, MFM-130 and MFM-131 (MFM = Manchester Framework Material), ha...
Two metal–organic framework materials, MFM-130 and MFM-131 (MFM = Manchester Framework Material), ha...
Metal-organic frameworks (MOFs) are a class of porous materials that are formed when inorganic metal...
Metal–organic frameworks have emerged as a class of porous materials with structures that can be def...
Sem informaçãoThe synthesis of stable porous materials with appropriate pore size and shape for desi...
Metal–organic frameworks have emerged as a class of porous materials with structures that can be def...
Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydrox...
Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydrox...
Four isostructural CPO‐54‐M metal‐organic frameworks based on the larger organic linker 1,5‐dihydrox...
Metal-organic frameworks are a new class of porous materials that have potential applications in gas...
By using three rigid diisophthalate organic linkers incorporating different numbers and orientations...
Despite their having much greater potential for compositional and structural diversity, heterometall...
The work herein describes progress toward designing, synthesizing, and characterizing new metal–orga...
The work herein describes progress toward designing, synthesizing, and characterizing new metal–orga...
Two metal–organic framework materials, MFM-130 and MFM-131 (MFM = Manchester Framework Material), ha...
Two metal–organic framework materials, MFM-130 and MFM-131 (MFM = Manchester Framework Material), ha...
Two metal–organic framework materials, MFM-130 and MFM-131 (MFM = Manchester Framework Material), ha...
Metal-organic frameworks (MOFs) are a class of porous materials that are formed when inorganic metal...
Metal–organic frameworks have emerged as a class of porous materials with structures that can be def...
Sem informaçãoThe synthesis of stable porous materials with appropriate pore size and shape for desi...
Metal–organic frameworks have emerged as a class of porous materials with structures that can be def...