The charge-dependent structure of interfacial water at the n-Ge(100)-aqueous perchlorate interface was studied by controlling the electrode potential. Specifically, a joint attenuated total reflection infrared spectroscopy and electrochemical experiment was used in 0.1M NaClO4 at pH ≈ 1–10. The germanium surface transformation to an H-terminated surface followed the thermodynamic Nernstian pH dependence and was observed throughout the entire pH range. A singular value decomposition-based spectra deconvolution technique coupled to a sigmoidal transition model for the potential dependence of the main components in the spectra shows the surface transformation to be a two-stage process. The first stage was observed together with the first appea...
The air-liquid interface of aqueous hydrogen-halide solutions is examined using vibrational sum freq...
The structure and orientation of water molecules on Au(1 1 1-20nm) film electrodes in contact with a...
The properties and behavior of water at interfaces is important in many fields. However, it is not c...
The electrode potential dependence of the hydration layer on an n-Ge(100) surface was studied by a c...
In acidic solution, germanium surfaces undergo a transformation to hydrogen-terminated surfaces at s...
The electric double layer governs the processes of all charged surfaces in aqueous solutions; howeve...
Structural changes of the hydration shell of surfaces in aqueous solution are studied using attenuat...
Over the past years, it has been found that understanding the metal/water interaction plays a vital ...
Phase-sensitive sum-frequency vibrational spectroscopy was used to study water/vapor interfaces of H...
Die ladungsabhängige Struktur von Grenzflächenwasser auf n-Ge (100) und (111) Oberflächen wurde mitt...
The effect of the surface electric field on the ultrafast vibrational dynamics of interfacial water ...
Measurement of the interfacial capacity of germanium electrodes in aqueous solutions of pH 4.5-11.5 ...
Structural change of the water layers is the primary step for the direct interactions among the hydr...
Infrared–visible sum-frequency generation (SFG) spectroscopy has been used to study the structure of...
Some salts have been recently shown to decrease the sum frequency generation (SFG) intensity of the ...
The air-liquid interface of aqueous hydrogen-halide solutions is examined using vibrational sum freq...
The structure and orientation of water molecules on Au(1 1 1-20nm) film electrodes in contact with a...
The properties and behavior of water at interfaces is important in many fields. However, it is not c...
The electrode potential dependence of the hydration layer on an n-Ge(100) surface was studied by a c...
In acidic solution, germanium surfaces undergo a transformation to hydrogen-terminated surfaces at s...
The electric double layer governs the processes of all charged surfaces in aqueous solutions; howeve...
Structural changes of the hydration shell of surfaces in aqueous solution are studied using attenuat...
Over the past years, it has been found that understanding the metal/water interaction plays a vital ...
Phase-sensitive sum-frequency vibrational spectroscopy was used to study water/vapor interfaces of H...
Die ladungsabhängige Struktur von Grenzflächenwasser auf n-Ge (100) und (111) Oberflächen wurde mitt...
The effect of the surface electric field on the ultrafast vibrational dynamics of interfacial water ...
Measurement of the interfacial capacity of germanium electrodes in aqueous solutions of pH 4.5-11.5 ...
Structural change of the water layers is the primary step for the direct interactions among the hydr...
Infrared–visible sum-frequency generation (SFG) spectroscopy has been used to study the structure of...
Some salts have been recently shown to decrease the sum frequency generation (SFG) intensity of the ...
The air-liquid interface of aqueous hydrogen-halide solutions is examined using vibrational sum freq...
The structure and orientation of water molecules on Au(1 1 1-20nm) film electrodes in contact with a...
The properties and behavior of water at interfaces is important in many fields. However, it is not c...