Dielectric Spectroscopy of Bisphenol A Epoxy Resin Aged in Wet and Dry Conditions

This thesis presents the laboratory test data on Bisphenol A epoxy insulation.This thesis work deals with electrical, mechanical and thermal analysis of Bisphenol A epoxy resin. The main aim of this thesis work was to examine if dry and wet aging changes the glass transition temperature (Tg) of the epoxies and measure the impact on the complex permittivity under different ageing conditions namely dry and wet. During ageing the samples (epoxy discs and dog bones) were kept in water at 20°C, 45°C and 80°C both in dry and wet conditions for a period of one month. After the samples were removed from ageing they were conditioned in a vacuum oven for one week. The effect of temperature and relative humidity on unaged epoxy i.e. dry characterization was determined by keeping the samples in climate chamber with 15%RH (Relative Humidity) and temperatures 20°C, 45°C and 80°C. The wet characterization was carried out with 90%RH and temperatures 20°C, 45°C and 80°C. The surface of these samples was painted with silver paint (electrodes). Two circular discs were used for dielectric response measurement and 2 rectangular pieces for water sorption measurement. The dielectric response was measured when equilibrium/saturation condition was achieved. The dielectric response was measured in the frequency range from 0.01 Hz to 1000 Hz at 200 volts (peak). The wet characterization showed increases with aging temperature. The dielectric loss was also increasing with the temperature. It can be deduced that the water uptake by the epoxy increases with increase in humidity and temperature. The dry characterization showed and has steady growth with aging temperature. Therefore it can be deduced that characterization done in dry condition didn t significantly affect the complex permittivity as compared with wet characterization. The glass transition temperature (Tg) of the samples were found using DSC (Differential Scanning Calorimetry) with a heating rate 20°C/min. The Tg was measured in the samples in dry condition before the water absorption process, then in samples after the water absorption process with moisture in the sample, and then in sample after the desorption. The effect of water on the Tg of the epoxy polymer was studied. Tg was increasing with aging temperature, for both dry as well as wet samples. The increase in the value can be mainly attributed to post curing process of the epoxy. The mechanical strength of the epoxy was studied by applying a tensile force to the dog bone shaped samples till breakdown and the stress versus strain curve was detected. This test was also performed on the dry aged sample before water absorption, then in sample which was kept under water at 20°C ,45°C and 80°C for absorption, and in sample which has undergone absorption and desorption at 20°C ,45°C and 80°C. The difference between the stress-strain curves was documented and discussed. The ageing temperature plays a significant role in reducing the value of stress and percentage strain at max. For dry aged epoxy, stress reduces around 14% from 200C to 800C. However for wet aged epoxy samples tensile strength reduces around 25%. For dry aged samples % strain reduces around 0,3 %. and for wet aged samples it reduces around 0,5%