Direct electrochemical reduction of hematite pellets in alkaline solutions

Our previous studies on the electrowinning of iron from hematite particles suspended in sodium hydroxide solutions demonstrated that iron was produced through a direct solid phase electrochemical reduction of the oxide particles. This suggests that the electro-deoxidation of a hematite powder pellet by the FFC type process should be possible in aqueous solutions at a low temperature. We investigated the electrochemical reduction of a solid hematite pellet cathode manufactured by conventional mechanical pressing followed by sintering process in concentrated sodium hydroxide solutions using a nickel inert anode at 110 °C. The experimental results indicated that hematite was reduced to iron metal. Propagation of the reduction reaction front through the oxide phase occurred at a high speed, and the rate-determining step was the diffusion of the oxygen ion through the shrinking cores of the oxide particle