Thesis explores the self- assembly and reaction of molecules on surfaces. Initial focus was on understanding these molecular behaviours on metal surfaces by examining the chemical and electronic properties. Unfortunately, metal surfaces are unsuitable for electronic applications. Hence, subsequent focus was on transitioning the experiment to non-metallic and low-cost silicon surfaces. Silicon requires to be passivated with metal atom layers due to its high reactivity. Molecular behaviour was examined by varying the metal layer thickness. Metal layers with 20 atoms thickness mimics the bulk metal surfaces, thus provide an economical and practical alternative platform for the study of molecular dynamics
In order to achieve accurate energetics for surface reactions, first-principles calculations are per...
Terephthalic acid (TPA) deposited on Si(111)-7 x 7, Si(111)-root 3 x root 3-Ag and Ag(111) has been ...
Contains an introduction, reports on two research projects and a list of publications.Joint Services...
The discipline of surface chemistry has rapidly expanded within recent years, attaining richness and...
International audienceNowadays more than 90% of published results show molecules adsorbed onto metal...
Teplyakov, Andrew V.As massive attempts are focused on crafting thinner films, the surfaces involved...
The creation of electronic devices only from atoms or molecules could be the next step in the creati...
Using ab initio generalized valence bond (GVB) and configuration interaction (CI) methods with clus...
When small metal assembles such as single atoms or small clusters consisting of a few atoms are supp...
Molecular electronics is recognized as a key candidate to succeed the silicon based technology as so...
Exploiting coordination bonding of aromatic carboxylic acids at metal surfaces, this thesis explores...
The use of nucleophilic displacement reactions on bromine-terminated monolayers is presented to crea...
The fundamental understanding of silicon surface chemistry is an essential tool for silicon\u27s con...
Terephthalic acid (TPA) deposited on Si(111)-7 7, Si(111)- ffiffiffi3p ffiffiffi3p-Ag and Ag(111) ...
Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2000.Includes bibliograph...
In order to achieve accurate energetics for surface reactions, first-principles calculations are per...
Terephthalic acid (TPA) deposited on Si(111)-7 x 7, Si(111)-root 3 x root 3-Ag and Ag(111) has been ...
Contains an introduction, reports on two research projects and a list of publications.Joint Services...
The discipline of surface chemistry has rapidly expanded within recent years, attaining richness and...
International audienceNowadays more than 90% of published results show molecules adsorbed onto metal...
Teplyakov, Andrew V.As massive attempts are focused on crafting thinner films, the surfaces involved...
The creation of electronic devices only from atoms or molecules could be the next step in the creati...
Using ab initio generalized valence bond (GVB) and configuration interaction (CI) methods with clus...
When small metal assembles such as single atoms or small clusters consisting of a few atoms are supp...
Molecular electronics is recognized as a key candidate to succeed the silicon based technology as so...
Exploiting coordination bonding of aromatic carboxylic acids at metal surfaces, this thesis explores...
The use of nucleophilic displacement reactions on bromine-terminated monolayers is presented to crea...
The fundamental understanding of silicon surface chemistry is an essential tool for silicon\u27s con...
Terephthalic acid (TPA) deposited on Si(111)-7 7, Si(111)- ffiffiffi3p ffiffiffi3p-Ag and Ag(111) ...
Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2000.Includes bibliograph...
In order to achieve accurate energetics for surface reactions, first-principles calculations are per...
Terephthalic acid (TPA) deposited on Si(111)-7 x 7, Si(111)-root 3 x root 3-Ag and Ag(111) has been ...
Contains an introduction, reports on two research projects and a list of publications.Joint Services...