The evaluation of a series of camphor-derived ligands as catalysts in the asymmetric Henry reaction is reported. The synthesis of two novel derivatives is detailed and these molecules are also screened as catalysts in this reaction. The single crystal X-ray structure of one of the novel compounds is reported. The reaction is catalyzed with moderate to excellent yields and moderate enantioselectivity.Keywords: Camphor, asymmetric catalysis, Henry reaction, chiral ligand
Several camphor and pinane derivatives have been synthesised and evaluated for use as chiral auxilia...
The work to be presented herein illustrates several important facts. First, the synthesis of BIBOL ...
Factors which influence the diastereoselectivity in the alkylation of the (R)-camphor imine of tert-...
Thesis (M.Sc.)-University of KwaZulu-Natal, Durban, 2006.Chiral crown ethers have recently been show...
A new chiral tetrahydrosalen ligand has been designed and synthesized from <i>cis</i>-2,5-diaminobic...
The synthesis of a series of five novel precursor compounds derived from (R)-(+)-camphor is reported...
[[abstract]]ABSTRACT Design and Synthesis of Novel Camphor Derived Chiral Auxiliary/Ligands and Thei...
This thesis is intended to further extend the scope of camphor and camphor-derived building blocks i...
A new asymmetric synthesis of the antibiotic Linezolid was performed through a copper-catalyzed Henr...
-A novel C1-symmetric dinitrogen ligand was synthesized in high yield from commercially available (1...
Over the years, asymmetric catalysis has taken on increasingly central in enantioselective synthesis...
A series of novel tridentate Schiff bases is synthesized from piperazine-amine and substituted salic...
A C2-symmetric diethyl iPr-bis(oxazoline)–Cu(OAc)2·H2O was found to be an efficient catalyst for cat...
Recently, a novel chiral cubane-based Schiff base ligand was reported to yield modest enantioselecti...
The investigation has been focussed largely on the chemistry and stereo-directing potential of camph...
Several camphor and pinane derivatives have been synthesised and evaluated for use as chiral auxilia...
The work to be presented herein illustrates several important facts. First, the synthesis of BIBOL ...
Factors which influence the diastereoselectivity in the alkylation of the (R)-camphor imine of tert-...
Thesis (M.Sc.)-University of KwaZulu-Natal, Durban, 2006.Chiral crown ethers have recently been show...
A new chiral tetrahydrosalen ligand has been designed and synthesized from <i>cis</i>-2,5-diaminobic...
The synthesis of a series of five novel precursor compounds derived from (R)-(+)-camphor is reported...
[[abstract]]ABSTRACT Design and Synthesis of Novel Camphor Derived Chiral Auxiliary/Ligands and Thei...
This thesis is intended to further extend the scope of camphor and camphor-derived building blocks i...
A new asymmetric synthesis of the antibiotic Linezolid was performed through a copper-catalyzed Henr...
-A novel C1-symmetric dinitrogen ligand was synthesized in high yield from commercially available (1...
Over the years, asymmetric catalysis has taken on increasingly central in enantioselective synthesis...
A series of novel tridentate Schiff bases is synthesized from piperazine-amine and substituted salic...
A C2-symmetric diethyl iPr-bis(oxazoline)–Cu(OAc)2·H2O was found to be an efficient catalyst for cat...
Recently, a novel chiral cubane-based Schiff base ligand was reported to yield modest enantioselecti...
The investigation has been focussed largely on the chemistry and stereo-directing potential of camph...
Several camphor and pinane derivatives have been synthesised and evaluated for use as chiral auxilia...
The work to be presented herein illustrates several important facts. First, the synthesis of BIBOL ...
Factors which influence the diastereoselectivity in the alkylation of the (R)-camphor imine of tert-...