Coordination behaviour of 3-hydroxypicolinamide (HPA) towards TbIII is studied in aqueous and micellar media. The complex formed exists asML2 species in which HPA behaves as anO,O,N,N-chelating ligand. The solid complex is isolated from aqueous medium and characterized employing elemental analysis, TG/DTA, magnetic, IR, ESR and mass spectral data. Stability constant and other accompanying thermodynamic parameters of the TbIII complex have been determined pHmetrically. The complexation reaction is spontaneous and exothermic. Effect of micelles andpHon the luminescence of TbIII were also studied. The emission peaks of TbIII are highly sensitized on complexation with HPA and the optimum luminescence efficiency is obtained in slightly acidic ...
Four new macrocyclic-phthalimide ligands were synthesised via the coupling of N-(3-bromopropyl)phtha...
The possibility of determination of total bitter substances content in hops by sensitized Tb(III) io...
To serve well as luminescent labels in biological applications, complexes of the lanthanide ions nee...
The amorphous coordination compounds of terbium (III) and europium (III) with methyl ester of 2-hydr...
Luminescent properties of the complex Tb (III) with ciprofloxacin in micellar solution lauryl glutam...
Two luminescent terbium(III) complexes have been prepared from chiral ligands containing 2-hydroxyis...
A Tb(III) – 2,2’-dipyridyl complex as a luminescent sensor for determination of p-hydroxybenzoic aci...
The work introduces the temperature induced quenching of Tb(III) and Eu(III) centered luminescence s...
The work introduces the temperature induced quenching of Tb(III) and Eu(III) centered luminescence s...
The work introduces the temperature induced quenching of Tb(III) and Eu(III) centered luminescence s...
In this study, we investigated the effect of terbium ions (Tb3+) on the subphases of the limiting ar...
The synthesis, structural investigation, and photophysical properties of the complex [Tb(TTA)(2)(NO3...
Binary and ternary terbium complexes were synthesized: Tb (N-PA)(3) . 4H(2)O and Tb (N-PA)(3) (phen ...
The synthesis, structural investigation, and photophysical properties of the complex [Tb(TTA)(2)(NO(...
A series of new solid ternary complexes of terbium(III) ion based on β-diketone ligand acetylacetone...
Four new macrocyclic-phthalimide ligands were synthesised via the coupling of N-(3-bromopropyl)phtha...
The possibility of determination of total bitter substances content in hops by sensitized Tb(III) io...
To serve well as luminescent labels in biological applications, complexes of the lanthanide ions nee...
The amorphous coordination compounds of terbium (III) and europium (III) with methyl ester of 2-hydr...
Luminescent properties of the complex Tb (III) with ciprofloxacin in micellar solution lauryl glutam...
Two luminescent terbium(III) complexes have been prepared from chiral ligands containing 2-hydroxyis...
A Tb(III) – 2,2’-dipyridyl complex as a luminescent sensor for determination of p-hydroxybenzoic aci...
The work introduces the temperature induced quenching of Tb(III) and Eu(III) centered luminescence s...
The work introduces the temperature induced quenching of Tb(III) and Eu(III) centered luminescence s...
The work introduces the temperature induced quenching of Tb(III) and Eu(III) centered luminescence s...
In this study, we investigated the effect of terbium ions (Tb3+) on the subphases of the limiting ar...
The synthesis, structural investigation, and photophysical properties of the complex [Tb(TTA)(2)(NO3...
Binary and ternary terbium complexes were synthesized: Tb (N-PA)(3) . 4H(2)O and Tb (N-PA)(3) (phen ...
The synthesis, structural investigation, and photophysical properties of the complex [Tb(TTA)(2)(NO(...
A series of new solid ternary complexes of terbium(III) ion based on β-diketone ligand acetylacetone...
Four new macrocyclic-phthalimide ligands were synthesised via the coupling of N-(3-bromopropyl)phtha...
The possibility of determination of total bitter substances content in hops by sensitized Tb(III) io...
To serve well as luminescent labels in biological applications, complexes of the lanthanide ions nee...