Add to ORKGThe last decade has witnessed enormous growth in the asymmetric synthetic applications of dirhodium(II) carbenes generated from diazo-precursors. Innovative construction of 'designer' catalysts has played an integral role in extending the breadth of the synthetic cascade of non-racemic products now available through a range of cyclopropanation, C-X insertion, aromatic cycloaddition-rearrangement, and ylide-based reaction types. This review, whilst mindful of importance of the catalytic system, focuses primarily on the latter feature of product diversity. South African Journal of Chemistry Vol.54 2001: 1-4
Metal-catalyzed cyclopropanation of olefins with diazo reagents has attracted research interest beca...
This dissertation describes the engineering and evolution of dirhodium artificial metalloenzymes (Ar...
This dissertation presents three major projects. The first is the development of binaphthyl-based ch...
The last decade has witnessed enormous growth in the spectrum of highly efficient asymmetric synthet...
An efficient and reliable procedure for the preparation of dirhodium(II) tetrakis[N-phthaloyI-(S)-te...
This thesis is concerned with the examination of the broadly applied and highly effective dirhodium ...
International audienceIn this issue of Chem Catalysis, Zhang, Ma, Marek, et al. report a highly enan...
The title compounds are effective catalysts for intermolecular cyclopropenation reactions of 1-alkyn...
Dirhodium tetrakis-(<i>R</i>)-(1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylate) (Rh<sub>2</sub...
Methods for enantioselective transfer of carbenes starting from precursors carrying two carbonyl gro...
Summary.: The dirhodium(II)-catalyzed intermolecular cyclopropanation of a set of olefins with eithe...
In this issue of Chem Catalysis, Wang et al. report the synthesis of 1,1-cyclopropanediesters promot...
A planar chiral dirhodium paddlewheel complex Rh$_{2}$(S $_{p}$−PCP)$_{4}$ based on the [2.2]paracyc...
A planar chiral dirhodium paddlewheel complex Rh-2(S-p-PCP)(4)based on the [2.2]paracyclophane has b...
The Rh¹¹‐catalyzed carbenoid addition of diazoacetates to olefins was investigated with [Rh₂{(4S)‐ph...
Metal-catalyzed cyclopropanation of olefins with diazo reagents has attracted research interest beca...
This dissertation describes the engineering and evolution of dirhodium artificial metalloenzymes (Ar...
This dissertation presents three major projects. The first is the development of binaphthyl-based ch...
The last decade has witnessed enormous growth in the spectrum of highly efficient asymmetric synthet...
An efficient and reliable procedure for the preparation of dirhodium(II) tetrakis[N-phthaloyI-(S)-te...
This thesis is concerned with the examination of the broadly applied and highly effective dirhodium ...
International audienceIn this issue of Chem Catalysis, Zhang, Ma, Marek, et al. report a highly enan...
The title compounds are effective catalysts for intermolecular cyclopropenation reactions of 1-alkyn...
Dirhodium tetrakis-(<i>R</i>)-(1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylate) (Rh<sub>2</sub...
Methods for enantioselective transfer of carbenes starting from precursors carrying two carbonyl gro...
Summary.: The dirhodium(II)-catalyzed intermolecular cyclopropanation of a set of olefins with eithe...
In this issue of Chem Catalysis, Wang et al. report the synthesis of 1,1-cyclopropanediesters promot...
A planar chiral dirhodium paddlewheel complex Rh$_{2}$(S $_{p}$−PCP)$_{4}$ based on the [2.2]paracyc...
A planar chiral dirhodium paddlewheel complex Rh-2(S-p-PCP)(4)based on the [2.2]paracyclophane has b...
The Rh¹¹‐catalyzed carbenoid addition of diazoacetates to olefins was investigated with [Rh₂{(4S)‐ph...
Metal-catalyzed cyclopropanation of olefins with diazo reagents has attracted research interest beca...
This dissertation describes the engineering and evolution of dirhodium artificial metalloenzymes (Ar...
This dissertation presents three major projects. The first is the development of binaphthyl-based ch...