Progress in the synthesis and applications of hexaaluminate-based catalysts

The development of materials that can exhibit thermal resistance at very high temperatures, thus allowing them to be applied as catalysts and thermal insulators, amongst other possible uses, is a research subject of great interest. This is the case for hexaaluminates, a class of hexagonal aluminate compounds with a unique structure that are stable at very high temperatures up to 1600°C and exhibit exceptional resistance to sintering and thermal shock, thus making them attractive catalysts for high-temperature applications. In this review, the structure of hexaaluminates is presented first. The most recent advances in synthetic methods (sol-gel, reverse microemulsion, hydrothermal synthesis, carbon-templating, solution combustion synthesis, and freeze-drying methods) are discussed subsequently, with the aim of maximizing textural properties and including in their structure metals known to be active in catalytic applications, such as combustion of CH4, partial oxidation, and dry reforming of CH4 to produce synthetic gas, and the decomposition of N2O. Finally, other applications, such as their function as a thermal barrier, are also addressed.The authors are grateful for financial support from the Spanish Ministry of Economy, Industry, and Competitiveness (AEI/MINECO), the European Regional Development Fund (ERDF) through project MAT2016-78863-C2-R. JJTH thanks Universidad Pública de Navarra for a pre-doctoral grant. AG also thanks Santander Bank for funding via the Research Intensification Program