International audienceSeries of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symmetric N-heterocyclic carbenes were synthesized from achiral precursors. The chirality of theses complexes results from the formation of the carbene-palladium bond which restricts the rotation of dissymmetric N-aryl substituents of the NHC and thus creates an axis of chirality. Chiral HPLC at preparative scale enabled the resolution of racemic complexes and provided a straightforward access to complexes with excellent enantiopurities (>99.5% ee). Enantiopure complexes were studied by crystal X-ray diffraction and electronic circular dichroism (ECD). Their configuration stabilities were investigated both experimentally and theoretically through ...
A series of three chiral, expanded six-membered NHC–palladium(II) complexes was prepared with succes...
A series of three chiral, expanded six-membered NHC–palladium(II) complexes was prepared with succes...
This picture illustrates the following publication: C2-Symmetric Atropisomeric N-Heterocyclic Carben...
International audienceSeries of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symme...
International audienceSeries of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symme...
International audienceSeries of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symme...
International audienceSeries of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symme...
International audienceThe concept of atropisomeric N-heterocyclic carbene (NHC)–metal complexes was ...
International audienceThe concept of atropisomeric N-heterocyclic carbene (NHC)–metal complexes was ...
International audienceThe concept of atropisomeric N-heterocyclic carbene (NHC)–metal complexes was ...
International audienceFrom achiral imidazolinium salts, chiral transition metal complexes containing...
International audienceFrom achiral imidazolinium salts, chiral transition metal complexes containing...
International audienceFrom achiral imidazolinium salts, chiral transition metal complexes containing...
International audienceFrom achiral imidazolinium salts, chiral transition metal complexes containing...
A series of three chiral, expanded six-membered NHC–palladium(II) complexes was prepared with succes...
A series of three chiral, expanded six-membered NHC–palladium(II) complexes was prepared with succes...
A series of three chiral, expanded six-membered NHC–palladium(II) complexes was prepared with succes...
This picture illustrates the following publication: C2-Symmetric Atropisomeric N-Heterocyclic Carben...
International audienceSeries of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symme...
International audienceSeries of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symme...
International audienceSeries of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symme...
International audienceSeries of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symme...
International audienceThe concept of atropisomeric N-heterocyclic carbene (NHC)–metal complexes was ...
International audienceThe concept of atropisomeric N-heterocyclic carbene (NHC)–metal complexes was ...
International audienceThe concept of atropisomeric N-heterocyclic carbene (NHC)–metal complexes was ...
International audienceFrom achiral imidazolinium salts, chiral transition metal complexes containing...
International audienceFrom achiral imidazolinium salts, chiral transition metal complexes containing...
International audienceFrom achiral imidazolinium salts, chiral transition metal complexes containing...
International audienceFrom achiral imidazolinium salts, chiral transition metal complexes containing...
A series of three chiral, expanded six-membered NHC–palladium(II) complexes was prepared with succes...
A series of three chiral, expanded six-membered NHC–palladium(II) complexes was prepared with succes...
A series of three chiral, expanded six-membered NHC–palladium(II) complexes was prepared with succes...
This picture illustrates the following publication: C2-Symmetric Atropisomeric N-Heterocyclic Carben...