Caves are among Earth\u27s most important minerogenetic environments and they host over 350 minerals, some of them new for science. The presence of such an unexpected richness is a direct consequence of the variety of rocks traversed by water or other fluids before entering a cave and the sediments therein. In the last 50 years, systematic studies defined the genetic mechanisms for nearly all speleothem types and the physico-chemical processes involved in their deposition. Speleothems are extremely important from a scientific standpoint as they proved to be the best archives to reconstruct Quaternary climates, environments, and seismic activity. Up to present rather all cave scientific research involved calcium carbonate speleothems. Yet, r...