Ruthenium-catalyzed cascade N- and C(3)-dialkylation of cyclic amines with alcohols involving hydrogen autotransfer processes
- Sundararaju, B.
- Tang, Z.
- Achard, Mathieu
- V. M. Sharma, G.
- Toupet, Loïc
- Bruneau, Christian
DOIAbstract
International audienceAn unprecented N- and C(3)-dialkylation of unactivated amines by a cascade reaction via borrowing hydrogen methodology using new (arene)ruthenium(II) complexes featuring phosphinosulfonate ligands is described. This reaction is highly regioselective and produces water as the only side product
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