Interfacial and Permeating Modification Effect of n‑type Non-fullerene Acceptors toward High-Performance Perovskite Solar Cells

Interface passivation in the electron transport layer (ETL) has emerged as a very important and challenging topic for the improvement of stability and efficiency of perovskite solar cells (PSCs). Here, we introduce the n-type small organic molecule Y6 that acts as an effective ETL modifier through surface engineering. As a result, the simple PCBM + Y6 ETL led to significantly stronger light absorption, higher electron extraction ability and transportability, and reduced recombination loss in regular MAPbI3 PSCs. The power conversion efficiency can be significantly increased from 17.39 to 20.02% in inverted p–i–n MAPbI3 PSCs without additional alternation, with an increment of over 15%, along with higher open-circuit voltage and short-circuit current. What is more, the devices with the Y6-modified ETL also exhibited better long-term stability compared to the control devices. This indicates the feasibility of enhancing absorption over a wider light spectrum in a single-junction cell and gaining a comprehensive understanding of interface engineering between the ETL and perovskite layer