With alkyl carbazates as the green ester source, a novel palladium-catalyzed oxidative free radical carbonylative transformation of the C–H bond on aromatic rings to produce esters has been developed. Good yields of the corresponding products have been obtained with wide functional group tolerance and excellent regioselectivity. A variety of alkyl carbazates are found to be suitable reactants for the ortho-alkoxycarbonylation on the aromatic ring. We report an environmentally benign protocol for the C–H alkoxycarbonylation of arenes with alkylcarbazates directed by N-heterocyclic substituents. Pd(OAc)2 is used to catalyze this oxidative free radical carbonylative transformation. The reaction is tolerant to a wide variety of functional gr...
A mild protocol has been developed for the Pd-catalyzed alkoxycarbonylation of terminal olefins to p...
Green Friedel–Crafts acylation reactions belong to the most desired transformations in organic chemi...
A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbon...
A palladium catalyzed ortho-alkoxylation of aryl C-H bond was accomplished with primary and secondar...
A direct and facile palladium-catalyzed C–H bond oxidative carbonylation reaction and oxidative cycl...
A catalytic C–H alkylation using unactivated alkyl halides and a variety of arenes and heteroarenes ...
The overall goal of this project is the development of new catalytic strategies for the construction...
xix, 271 p. : ill. ; 30 cm.PolyU Library Call No.: [THS] LG51 .H577P ABCT 2010 SitDevelopment of cat...
Herein we reported a Pd-catalyzed ortho-acetoxylation of arenes through a six-membered system using ...
Recent trends in research have gained an orientation towards developing efficient strategies using i...
A catalytic C–H alkylation using unactivated alkyl halides and a variety of arenes and heteroarenes ...
International audienceThe N‐tosylcarboxamide group can direct the room‐temperature palladium‐catalyz...
tA new protocol for the alkoxycarbonylation of -olefins to the corresponding unsaturated esters hasb...
The ability to selectively functionalize complex molecules is an ongoing challenge to chemists; the ...
In the first part of the thesis, the aim was to devise a new simple catalytic system based on pallad...
A mild protocol has been developed for the Pd-catalyzed alkoxycarbonylation of terminal olefins to p...
Green Friedel–Crafts acylation reactions belong to the most desired transformations in organic chemi...
A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbon...
A palladium catalyzed ortho-alkoxylation of aryl C-H bond was accomplished with primary and secondar...
A direct and facile palladium-catalyzed C–H bond oxidative carbonylation reaction and oxidative cycl...
A catalytic C–H alkylation using unactivated alkyl halides and a variety of arenes and heteroarenes ...
The overall goal of this project is the development of new catalytic strategies for the construction...
xix, 271 p. : ill. ; 30 cm.PolyU Library Call No.: [THS] LG51 .H577P ABCT 2010 SitDevelopment of cat...
Herein we reported a Pd-catalyzed ortho-acetoxylation of arenes through a six-membered system using ...
Recent trends in research have gained an orientation towards developing efficient strategies using i...
A catalytic C–H alkylation using unactivated alkyl halides and a variety of arenes and heteroarenes ...
International audienceThe N‐tosylcarboxamide group can direct the room‐temperature palladium‐catalyz...
tA new protocol for the alkoxycarbonylation of -olefins to the corresponding unsaturated esters hasb...
The ability to selectively functionalize complex molecules is an ongoing challenge to chemists; the ...
In the first part of the thesis, the aim was to devise a new simple catalytic system based on pallad...
A mild protocol has been developed for the Pd-catalyzed alkoxycarbonylation of terminal olefins to p...
Green Friedel–Crafts acylation reactions belong to the most desired transformations in organic chemi...
A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbon...