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Copper(I)-catalysed site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T

  • Jianwen Jin
  • Yichao Zhao
  • Sara Helen Kyne
  • Kaveh Farshadfar
  • Alireza Ariafard
  • Philip Wai Hong Chan
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Publication date
July 2021
Icon DOI
10.1038/s41467-021-23988-y
Publisher
Springer Science and Business Media LLC
Journal
Nature Communications

Abstract

Organochlorides are widespread in natural products, therefore the methods for site-selective chlorination at specific C–H bonds are of great interest. Here, the authors report a copper(I)-catalysed synthetic method for the efficient site-selective C(sp 3)–H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T at room temperature

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