SbCl5—wet acetonitrile: a new system for chemoselective O-desilylation

Glória, Paulo M. C.
Prabhakar, Sundaresan
Lobo, Ana M.
Gomes, Mário

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Publication date

January 2003

DOI

10.1016/j.tetlet.2003.09.191

Publisher

Pergamon

ISSN

0040-4039

Journal

Tetrahedron Letters

Abstract

Abstract—A new efficient method for deprotection of TBDMS derivatives of phenols, primary alcohols, carboxylic acids and secondary amines, consisting of SbCl5 and MeCN with 0.1% water (w/v), is reported. It effects inter alia desilylation of a CH2OTBDMS group in the presence of a ketal function

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SbCl5—wet acetonitrile: a new system for chemoselective O-desilylation

Abstract

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SbCl5—wet acetonitrile: a new system for chemoselective O-desilylation

Abstract

Extracted data

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