Dielectric relaxation study of amorphous TiTaO thin films in a large operating temperature range

International audienceTwo relaxation processes have been identified in amorphous TiTaO thin films deposited by reactive magnetron sputtering. The parallel angle resolved x-ray photoelectron spectroscopy and field emission scanning electron microscopy analyses have shown that this material is composed of an agglomerates mixture of TiO2, Ta2O5, and Ti-Ta bonds. The first relaxation process appears at low temperature with activation energy of about 0.26 eV and is related to the first ionisation of oxygen vacancies and/or the reduction of Ti4+ to Ti3+. The second relaxation process occurs at high temperature with activation energy of 0.95 eV. This last peak is associated to the diffusion of the doubly ionized oxygen vacancies VÖ. The dispersion phenomena observed at high temperature can be attributed to the development of complex defect such as (VÖ − 2Ti3+)