We inquire into the possible coexistence of macroscopic and microstructured phases in random Q-block copolymers built of incompatible monomer types A and B with equal average concentrations. In our microscopic model, one block comprises M identical monomers. The block-type sequence distribution is Markovian and characterized by the correlation λ. Upon increasing the incompatibility χ (by decreasing temperature) in the disordered state, the known ordered phases form: for λ>λ(c), two coexisting macroscopic A- and B-rich phases, for λ<λ(c), a microstructured (lamellar) phase with wave number k(λ). In addition, we find a fourth region in the λ-χ plane where these three phases coexist, with different, non-Markovian sequence distributions (fracti...
We derive an order parameter model for triblock copolymers. After the statistical description of int...
We used the self-consistent field (SCF) formalism of Scheutjens and Fleer (SF-SCF) to complement exi...
Block copolymers with their rich phase behavior and ordering transitions have become a paradigm for ...
We inquire into the possible coexistence of macroscopic and microstructured phases in random Q-block...
A mean-field theory for domain structures in random multiblock copolymer melts is developed. We focu...
In this paper we present the results of a calculation of the phase diagram of a highly polydisperse ...
Statistische binäre Block-Copolymere entstehen durch permanente Bindung von Prä-Polymer-B...
Several novel aspects of the microphase separation transition of block copolymers have been studied....
A Landau free energy is derived for the weak segregation regime (WSR) of melts belonging to a very g...
The statistical theory of microphase separation in the ternary ABC triblock copolymers is presented...
Summary The main theme of this thesis is the influence of polydispersity on the phase behavior of co...
ABSTRACT: We study the lamellar phase formed by symmetric ABA triblock copolymers with degree of pol...
Summary The main theme of this thesis is the influence of polydispersity on the phase behavior of co...
Molecular-dynamics simulations are used to study the phase behavior of a single linear multiblock co...
The question we address in the thesis concerns the phase behavior of monodisperse multiblock copolym...
We derive an order parameter model for triblock copolymers. After the statistical description of int...
We used the self-consistent field (SCF) formalism of Scheutjens and Fleer (SF-SCF) to complement exi...
Block copolymers with their rich phase behavior and ordering transitions have become a paradigm for ...
We inquire into the possible coexistence of macroscopic and microstructured phases in random Q-block...
A mean-field theory for domain structures in random multiblock copolymer melts is developed. We focu...
In this paper we present the results of a calculation of the phase diagram of a highly polydisperse ...
Statistische binäre Block-Copolymere entstehen durch permanente Bindung von Prä-Polymer-B...
Several novel aspects of the microphase separation transition of block copolymers have been studied....
A Landau free energy is derived for the weak segregation regime (WSR) of melts belonging to a very g...
The statistical theory of microphase separation in the ternary ABC triblock copolymers is presented...
Summary The main theme of this thesis is the influence of polydispersity on the phase behavior of co...
ABSTRACT: We study the lamellar phase formed by symmetric ABA triblock copolymers with degree of pol...
Summary The main theme of this thesis is the influence of polydispersity on the phase behavior of co...
Molecular-dynamics simulations are used to study the phase behavior of a single linear multiblock co...
The question we address in the thesis concerns the phase behavior of monodisperse multiblock copolym...
We derive an order parameter model for triblock copolymers. After the statistical description of int...
We used the self-consistent field (SCF) formalism of Scheutjens and Fleer (SF-SCF) to complement exi...
Block copolymers with their rich phase behavior and ordering transitions have become a paradigm for ...