The formation and the thermal stability of silyl (SiH3) groups on Si(1 0 0) surfaces was investigated by mass spectrometry. Silyl groups were prepared either by adsorption and decomposition of disilane (Si2H6) on clean Si(1 0 0), or by using thermal hydrogen atoms to generate silicon hydride groups. The silyl coverage decreases with increasing temperature during disilane or H atom exposure. Maximum silyl coverages of 0.15 and 0.12 ML, respectively, were obtained after disilane or H atom saturation exposures at 110 K. On saturated Si(1 0 0) surfaces, i.e., in absence of dangling bonds, silyl groups are stable up to 500 K; above 500 K the formation of silane (SiH4) via disproportionation, -SiH3(a) + SiH2(a) --> SiH4(g) + SiH(a), was observed....
The Eley–Rideal reaction scheme in which H abstraction from the a-Si:H surface takes place by SiH3 r...
The Eley–Rideal reaction scheme in which H abstraction from the a-Si:H surface takes place by SiH3 r...
[[abstract]]Adsorption and thermal decomposition of H2S on Si(100)-2 x 1 are studied by means of tem...
The formation and the thermal stability of silyl (SiH3) groups on Si(1 0 0) surfaces was investigate...
The formation and the thermal stability of silyl (SiH3) groups on Si(1 0 0) surfaces was investigate...
Amorphous hydrogenated silicon (a-Si:H) films in the thickness range 0.1–4.5 nm were deposited on Si...
Amorphous hydrogenated silicon (a-Si:H) films in the thickness range 0.1–4.5 nm were deposited on Si...
The effect of atomic hydrogen on the adsorbed layers formed on Si(100) from ethylene and acetylene e...
Hydrogen-terminated Si(111) reacts thermally at moderate temperatures with alcohols (RCH\u2082OH) an...
The Si-Si, Ge-Ge, Si-Ge, Si-H, and Ge-H bonds are analyzed through $\rm Si\sb2H\sb6$ and $\rm Ge\sb2...
In this letter, we report results of a hydrosilylation carried out on bifunctional molecules by usin...
The density functional theory method is used to explore the mechanism of dissociative adsorption of ...
I hereby declare that I am the sole author of this thesis. This is a true copy of the thesis, includ...
The Eley–Rideal reaction scheme in which H abstraction from the a-Si:H surface takes place by SiH3 r...
The gas phase anhydrous reaction of glycidoxypropyldimethylethoxysilane (GPDMES) with a model hydrox...
The Eley–Rideal reaction scheme in which H abstraction from the a-Si:H surface takes place by SiH3 r...
The Eley–Rideal reaction scheme in which H abstraction from the a-Si:H surface takes place by SiH3 r...
[[abstract]]Adsorption and thermal decomposition of H2S on Si(100)-2 x 1 are studied by means of tem...
The formation and the thermal stability of silyl (SiH3) groups on Si(1 0 0) surfaces was investigate...
The formation and the thermal stability of silyl (SiH3) groups on Si(1 0 0) surfaces was investigate...
Amorphous hydrogenated silicon (a-Si:H) films in the thickness range 0.1–4.5 nm were deposited on Si...
Amorphous hydrogenated silicon (a-Si:H) films in the thickness range 0.1–4.5 nm were deposited on Si...
The effect of atomic hydrogen on the adsorbed layers formed on Si(100) from ethylene and acetylene e...
Hydrogen-terminated Si(111) reacts thermally at moderate temperatures with alcohols (RCH\u2082OH) an...
The Si-Si, Ge-Ge, Si-Ge, Si-H, and Ge-H bonds are analyzed through $\rm Si\sb2H\sb6$ and $\rm Ge\sb2...
In this letter, we report results of a hydrosilylation carried out on bifunctional molecules by usin...
The density functional theory method is used to explore the mechanism of dissociative adsorption of ...
I hereby declare that I am the sole author of this thesis. This is a true copy of the thesis, includ...
The Eley–Rideal reaction scheme in which H abstraction from the a-Si:H surface takes place by SiH3 r...
The gas phase anhydrous reaction of glycidoxypropyldimethylethoxysilane (GPDMES) with a model hydrox...
The Eley–Rideal reaction scheme in which H abstraction from the a-Si:H surface takes place by SiH3 r...
The Eley–Rideal reaction scheme in which H abstraction from the a-Si:H surface takes place by SiH3 r...
[[abstract]]Adsorption and thermal decomposition of H2S on Si(100)-2 x 1 are studied by means of tem...