Structure Characterization of Metal Oxide Clusters by Vibrational Spectroscopy: Possibilities and Prospects

This article summarizes the methodological progress that has been made in the vibrational spectroscopy of isolated polynuclear metal oxide clusters, with particular emphasis on free electron laser-based infrared action spectroscopy of gas phase clusters, over the last decade. The possibilities, limitations and prospects of the various experimental approaches are discussed using representative examples from pivotal studies in the field