Three novel polymetallic ruthenium (III) meso-tetra(4-pyridyl)porphyrins containing peripheral ""RuCl(3)(dppb)"" moieties have been prepared and characterized. The X-ray structure of the tetraruthenated {NiTPyP[RuCl(3)(dppb)](4)} porphyrin complex crystallizes in the triclinic space group FT. This structure is discussed and compared with the crystal data for the mer-[RuCl(3)(dppb)(py)]. The {TPyP[RuCl(3)(dppb)](4)} and {CoTPyP[RuCl(3)(dppb)](4)} porphyrins were used to obtain electrogenerated films on ITO and glass carbon electrode surfaces, respectively. Such tetraruthenated porphyrins form films of a mixed-valence species {TPyP[Ru(dppb)](4)(mu Cl(3))(2)}(2)(4n2+) and {CoTPyP[Ru(dppb)](4)(mu Cl(3))(2)}(2n)(4n2+) on the electrode surface. T...
A saddle shaped tetracluster porphyrin species containing four [Ru(3)O(OAc)(6)(py)(2)](+) clusters c...
Ruthenium(II) 5-(4′-sulfanylmethylphenyl)-10,15,20-triphenylporphyrin (Ru-TPP-SH) and manganese(III)...
Novas metaloporfirinas com complexos de rutênio do tipo {H2-TPyP[RuCl(dppb)(Xbipy)] 4}(PF6)4 e {M-TP...
Three novel polymetallic ruthenium (III) meso-tetra(4-pyridyl)porphyrins containing peripheral ""RuC...
A relevant series of symmetric supramolecular porphyrins has been obtained by attaching four [Ru II(...
The fabrication of supramolecular structures from the tetraruthenated porphyrin-containing phosphine...
Meso(3- and 4-pyridyl)porphyrins coordinated to four [Ru(bipy)2Cl]+ complexes, M(3-TRPyP) or M(4-TRP...
The first synthesis and electrochemistry of metalloporphyrins containing a bound PF, axial ligand ha...
A series of mixed-metal supramolecular porphyrin arrays in which the geometry of the central metal-p...
Supramolecular species combining ruthenium(II) polypyridines and tetrapyridylporphyrins (TPyP) have ...
Complexes derived from meso-tetra(thienyl)porphyrins (TThP) and meso-tetra(pyridyl)porphyrin (TP...
New tetraruthenated manganese (III) porphyrins were synthesized and characterized (P-31 NMR, cyclic ...
Artículo de publicación ISIThis work describes the preparation of a new tetraruthenated porphyrin an...
Uma nova série de metaloporfirinas supermoleculares não-planares foi obtida por meio de automontagem...
The spectroscopic and electrochemical properties of two isomeric forms of the supramolecular species...
A saddle shaped tetracluster porphyrin species containing four [Ru(3)O(OAc)(6)(py)(2)](+) clusters c...
Ruthenium(II) 5-(4′-sulfanylmethylphenyl)-10,15,20-triphenylporphyrin (Ru-TPP-SH) and manganese(III)...
Novas metaloporfirinas com complexos de rutênio do tipo {H2-TPyP[RuCl(dppb)(Xbipy)] 4}(PF6)4 e {M-TP...
Three novel polymetallic ruthenium (III) meso-tetra(4-pyridyl)porphyrins containing peripheral ""RuC...
A relevant series of symmetric supramolecular porphyrins has been obtained by attaching four [Ru II(...
The fabrication of supramolecular structures from the tetraruthenated porphyrin-containing phosphine...
Meso(3- and 4-pyridyl)porphyrins coordinated to four [Ru(bipy)2Cl]+ complexes, M(3-TRPyP) or M(4-TRP...
The first synthesis and electrochemistry of metalloporphyrins containing a bound PF, axial ligand ha...
A series of mixed-metal supramolecular porphyrin arrays in which the geometry of the central metal-p...
Supramolecular species combining ruthenium(II) polypyridines and tetrapyridylporphyrins (TPyP) have ...
Complexes derived from meso-tetra(thienyl)porphyrins (TThP) and meso-tetra(pyridyl)porphyrin (TP...
New tetraruthenated manganese (III) porphyrins were synthesized and characterized (P-31 NMR, cyclic ...
Artículo de publicación ISIThis work describes the preparation of a new tetraruthenated porphyrin an...
Uma nova série de metaloporfirinas supermoleculares não-planares foi obtida por meio de automontagem...
The spectroscopic and electrochemical properties of two isomeric forms of the supramolecular species...
A saddle shaped tetracluster porphyrin species containing four [Ru(3)O(OAc)(6)(py)(2)](+) clusters c...
Ruthenium(II) 5-(4′-sulfanylmethylphenyl)-10,15,20-triphenylporphyrin (Ru-TPP-SH) and manganese(III)...
Novas metaloporfirinas com complexos de rutênio do tipo {H2-TPyP[RuCl(dppb)(Xbipy)] 4}(PF6)4 e {M-TP...