Trabalho completo: acesso restrito, p.591–595he trans-[RuCl2(L)4], trans-[Ru(NO)Cl (L)4](PF6)2 (L = isonicotinamide and 4-acetylpyridine) and trans-[Ru(NO)(OH)(py)4]Cl2 (py = pyridine) complexes have been prepared and characterized by elemental analysis, UV–visible, infrared, and 1H NMR spectroscopies, and cyclic voltammetry. The MLCT band energies of trans-[RuCl2(L)4] increase in the order 4-acpy < isn < py. The reduction potentials of trans-[RuCl2(L)4] and trans-[Ru(NO)Cl(L)4]2+ increase in the order py < isn < 4-acpy. The stretching band frequency, νNO, of the nitrosyl complexes ranges from 1913 to 1852 cm−1 indicating a nitrosonium character for the NO ligand. Due to the large π-acceptor ability of the equatorial ligands, the coordinate...
The novel cyclometalated RU(III) complex, [Ru(η2-phpy)(trpy)Cl][PF6]·toluene 1, and the {Ru-NO}6 com...
The syntheses and characterization of new nitro complexes of Ru(II) with 2,4,6-tris(2-pyridyl)-1,3,5...
New ruthenium(II) complexes of type [Ru(bipy)2(L)](ClO4)·H2O are formed by the reaction of [Ru(bipy)...
The trans-[RUCl(2)(L)(4)], trans-[Ru(NO)Cl (L)(4)](PF(6))(2) (L = isonicotinamide and 4-acetylpyridi...
The trans-[RUCl(2)(L)(4)], trans-[Ru(NO)Cl (L)(4)](PF(6))(2) (L = isonicotinamide and 4-acetylpyridi...
Texto completo: acesso restrito. p. 93–96The cis to trans isomerizations during the syntheses of tra...
Texto completo: acesso restrito. p. 204-208The reaction of cis-dichloro(1,4,7,10-tetraazacyclododeca...
International audienceThe synthesis and behavior in water of a set of various cis(Cl,Cl)-[R-tpyRuCl2...
Ruthenium mononitro and mononitroso terpyridine complexes incorporating strong p-acidic azopyridine ...
The complex cis-[Ru(L-py)NO](3+) (I) (L-py = N-(2-methylpyridyl) 1,4,8,11-tetraazacyclotetradecane) ...
The reduction of the tetrafluoroborate salts of the ruthenium nitrosyl dicationic [Ru(η5-C5R5) (NO)(...
Two ruthenium nitrosyl porphyrins have been synthesized and characterized by spectroscopic and elect...
Two ruthenium nitrosyl porphyrins have been synthesized and characterized by spectroscopic and elect...
p. 5385-5392The synthesis, UV−vis spectra, and electrochemical behavior of the nitrile-bonded trans-...
Ruthenium mononitro and mononitroso terpyridine complexes incorporating strong pi -acidic azopyridin...
The novel cyclometalated RU(III) complex, [Ru(η2-phpy)(trpy)Cl][PF6]·toluene 1, and the {Ru-NO}6 com...
The syntheses and characterization of new nitro complexes of Ru(II) with 2,4,6-tris(2-pyridyl)-1,3,5...
New ruthenium(II) complexes of type [Ru(bipy)2(L)](ClO4)·H2O are formed by the reaction of [Ru(bipy)...
The trans-[RUCl(2)(L)(4)], trans-[Ru(NO)Cl (L)(4)](PF(6))(2) (L = isonicotinamide and 4-acetylpyridi...
The trans-[RUCl(2)(L)(4)], trans-[Ru(NO)Cl (L)(4)](PF(6))(2) (L = isonicotinamide and 4-acetylpyridi...
Texto completo: acesso restrito. p. 93–96The cis to trans isomerizations during the syntheses of tra...
Texto completo: acesso restrito. p. 204-208The reaction of cis-dichloro(1,4,7,10-tetraazacyclododeca...
International audienceThe synthesis and behavior in water of a set of various cis(Cl,Cl)-[R-tpyRuCl2...
Ruthenium mononitro and mononitroso terpyridine complexes incorporating strong p-acidic azopyridine ...
The complex cis-[Ru(L-py)NO](3+) (I) (L-py = N-(2-methylpyridyl) 1,4,8,11-tetraazacyclotetradecane) ...
The reduction of the tetrafluoroborate salts of the ruthenium nitrosyl dicationic [Ru(η5-C5R5) (NO)(...
Two ruthenium nitrosyl porphyrins have been synthesized and characterized by spectroscopic and elect...
Two ruthenium nitrosyl porphyrins have been synthesized and characterized by spectroscopic and elect...
p. 5385-5392The synthesis, UV−vis spectra, and electrochemical behavior of the nitrile-bonded trans-...
Ruthenium mononitro and mononitroso terpyridine complexes incorporating strong pi -acidic azopyridin...
The novel cyclometalated RU(III) complex, [Ru(η2-phpy)(trpy)Cl][PF6]·toluene 1, and the {Ru-NO}6 com...
The syntheses and characterization of new nitro complexes of Ru(II) with 2,4,6-tris(2-pyridyl)-1,3,5...
New ruthenium(II) complexes of type [Ru(bipy)2(L)](ClO4)·H2O are formed by the reaction of [Ru(bipy)...