Light-induced water oxidation at silicon electrodes functionalized with a cobalt oxygen-evolving catalyst

Integrating a silicon solar cell with a recently developed cobalt-based water-splitting catalyst (Co-Pi) yields a robust, monolithic, photo-assisted anode for the solar fuels process of water splitting to O2 at neutral pH. Deposition of the Co-Pi catalyst on the Indium Tin Oxide (ITO)-passivated p-side of a np-Si junction enables the majority of the voltage generated by the solar cell to be utilized for driving the water-splitting reaction. Operation under neutral pH conditions fosters enhanced stability of the anode as compared to operation under alkaline conditions (pH 14) for which long-term stability is much more problematic. This demonstration of a simple, robust construct for photo-assisted water splitting is an important step towards the development of inexpensive direct solar-to-fuel energy conversion technologies.Foundation for Fundamental Research on Matter (Netherlands)Netherlands Organization for Scientific ResearchNational Institutes of Health (U.S.) (NSF CHE-0533150)United States. Office of Naval Research ((AFOSR) FA9550-09-1-0689)Chesonis Family Foundatio