A new series of exTTF hosts has been synthesized for supramolecular binding study of fullerenes C60 and C70. Binding constants for C60 in chlorobenzene, toluene, toluene-CH2Cl2 and CS2 have been calculated for different hosts and a direct structure-affinity relationship has been established. As predicted, receptors with two exTTF moieties (1, 3 and 4) have demonstrated higher binding abilities toward C70 than C60. Depending on the linker used to attach the exTTF unit to the core of the host, different binding modes (1 : 1 and 2 : 1) have been obtained
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
A new series of exTTF hosts has been synthesized for supramolecular binding study of fullerenes C60 ...
International audienceExploiting the shape and electronic complementarity of C60 and C70 with π-exte...
International audienceExploiting the shape and electronic complementarity of C60 and C70 with π-exte...
bS Supporting Information ABSTRACT: Exploiting the shape and electronic complementarity of C60 and C...
Exploiting the shape and electronic complementarity of C60 and C70 with π-extended derivatives of te...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
A series of exTTF-(crown ether)2 receptors, designed to host C60, has been prepared. The size of the...
A calix[4]arene scaffolding has been used to construct bisporphyrin ("jaws" porphyrin) hosts for sup...
We report the use of a tetraborylated perylenediimide as starting material for the preparation of a ...
Fullerene receptors prepared by a twofold CuI -catalyzed azide-alkyne cycloaddition (CuAAC) reaction...
A cyclic porphyrin trimer has been synthesized which has a high affinity for fullerenes. It forms 1:...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
A new series of exTTF hosts has been synthesized for supramolecular binding study of fullerenes C60 ...
International audienceExploiting the shape and electronic complementarity of C60 and C70 with π-exte...
International audienceExploiting the shape and electronic complementarity of C60 and C70 with π-exte...
bS Supporting Information ABSTRACT: Exploiting the shape and electronic complementarity of C60 and C...
Exploiting the shape and electronic complementarity of C60 and C70 with π-extended derivatives of te...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
A series of exTTF-(crown ether)2 receptors, designed to host C60, has been prepared. The size of the...
A calix[4]arene scaffolding has been used to construct bisporphyrin ("jaws" porphyrin) hosts for sup...
We report the use of a tetraborylated perylenediimide as starting material for the preparation of a ...
Fullerene receptors prepared by a twofold CuI -catalyzed azide-alkyne cycloaddition (CuAAC) reaction...
A cyclic porphyrin trimer has been synthesized which has a high affinity for fullerenes. It forms 1:...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...
Fullerene receptors prepared by a twofold Cu-I-catalyzed azide-alkyne cycloaddition reaction with pi...