Rearrangements of dicarba-<i>nido-</i>undecaborates

  • S. P. Knyazev
  • A. Yu. Kostiykovitch
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Publication date
October 2011
Publisher
MIREA - Russian Technological University
Journal
Fine Chemical Technologies

Abstract

The thermal and chemically initiated thermal rearrangements of dicarba-nido-undecaborates was explored by computational chemistry. It was shown that the kinetic stability of dianions of these compounds is reduced in the series 2,9 &gt; 7,8 &gt; 1,7 &gt; 2,4 &gt; 2,8 &gt; 1,2 &gt;2,7 &gt; 2,3

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