Oxygen-permeable ceramic membrane with improved mediate-temperature stability based on partially A-site doped KxSr1-xCo0.8Fe0.2O3-δ

Practical application of SrCo0.8Fe0.2O3-–δ(SCF) perovskite oxide for oxygen separation is hindered by poor stability. Here, we developed new KxSr1–xCo0.8Fe0.2O3–δ membrane material by optimizing K+ doping in A-site of prototypical SCF. The partial substitution of Sr2+ with K+ can lead to the enhanced mechanical strength and intermediate-temperature oxygen permeation stability. It is found that the doping content of K+ should be lower than 20% because the excessive doping of K+ in A-site of SrCo0.8Fe0.2O3–δcan destroy their cubic perovskite structure. While x ≥ 0.2, some diffraction peaks different from cubic perovskite can be evidenced by X-ray diffraction and their oxygen permeation flux also decreases rapidly. Among the fabricated membranes, K0.1Sr0.9Co0.8Fe0.2O3–δexhibits the highest oxygen permeation flux (1.5 cm3 min−1 cm−2 at 950°C) under an air/He gradient. More important is that K0.1Sr0.9Co0.8Fe0.2O3–δ displays a stable oxygen permeation performance during over 120 h permeation operation at 750°C