Stereoselective assembly of a new pendant-arm macrocycle
- Bernhardt, Paul V.
- Byriel, Karl A.
- Kennard, Colin H. L.
- Sharpe, Philip C.
Publication date
January 1996
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
0300-9246 Citation count (estimate)
4Abstract
The new pendant-arm macrocycle (5S,7S,12R,14R)-tetramethyl-6,13 -dinitro-1,4,8,11-tetraazacyclotetradecane (L(1)) has been synthesised as its copper(II) complex and its crystal structure revealed a rare example of genuine square-planar co-ordination; reduction of [CuL(1)](2+) affords the metal-free diamino-substituted analogue
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